spring2008exam1

spring2008exam1 - Examination 1 SP08 CH222-Org.C hem l l N...

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Name Examination #1 - SP08 CH222-Org. Chem. ll t8l totateoints L Mechanisms. Write the complete (all arrows, charges, intermediates, NO TRANSITION STATES) for the following reactions. Show all stereochemistry using bold and dashed arrows where necessary. ANSWER 3 OF THE a PROBLEMS: WBITE OMIT ON THE tltlYtt-aI v vt rYE--trrYl lrrrla- vrltar vr! tf r- PROBLEM THAT YOU DO NOT WISH TO BE GRADED. C . C lsfB eacAl a o fl'f tra , (A) o\. . thenH+ +- "F HzO t cfb Hr ,^$:3rg \-\8. 0 -Hr ,-rS.,oH LA*. cH3 ,-t ot't ---|-t o{3 + Br2,HzO ----'> *r-U- ry +a0,. --? 40
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(C) HsC-C-C-H + H-,Hzo --+ v O ,il r, '. CA3-L=(, + H,P.' --+ W4:uL --"d H/-Y{ T *HO Clh ,cH3 cb-q:(" -'i)rc/ e# n ) It - u<Lt o H (D) HgC-C-CH2 + HBr, HzOz # p-@,iO-'U *) t {-{0' Jv [tor I A-,4( -+ Vr+a + $c o v (vt, Bv'$it-+ %-c.#r 3 Utry* + #$, #? C*t U-CIJ7 g/ 'il [ 4
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Write the major product(s) of the following reactions. Show the stereochemistry of the product
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This note was uploaded on 03/06/2010 for the course CH 222 taught by Professor Dr.nichols during the Spring '10 term at John Carroll.

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spring2008exam1 - Examination 1 SP08 CH222-Org.C hem l l N...

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