electron pushing 2 - Copy

electron pushing 2 - Copy - Chemistry 140A (Prof. C. L....

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-X Cl . CH 3 Cl Cl δ . H CH 3 δ . CH 3 . Cl H Cl . H CH 3 Cl . CH 3 Cl Cl δ . H CH 3 δ . Cl . CH 3 Cl CH 3 . Cl Cl H . H C C H H H H C C . H H H H Nu δ - R X δ - R + R X CH 3 Cl Cl R X CH 3 . Cl H Nu HO Cl HO CH 3 CH 3 CH CH 3 H AlCl 3 (CH 3 ) 3 N (CH 3 ) 3 N + AlCl 3 H . H Cl Cl . H CH 3 CH 3 δ . Cl Cl δ . CH 3 . Cl Cl H OH H 3 N OH H 3 N + H CH 3 CH CH 2 H Cl CH 3 CH . CH 3 X Nu R Electron Pushing to Generate Transition States for Radical Reactions = = Transition States for Nucleophilic Substitution Nu electrophile
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