Thermodynamic_Relations - dg(T, p) = - sdT + vdp...

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Thermodynamic Relations (simple compressible systems) The functions: p-v-T pressure, volume, temperature (eqs of state) e energy (internal, kinetic and potential) u internal energy h enthalpy (u + pv) s entropy ψ = u – Ts Helmholtz function g = h – Ts Gibbs function The state principle: for a simple compressible system the values of two, independent intensive properties define the state of the system. Principle exact differentials (Gibbs relations): du(s,v) = Tds – pdv dh(s,p) = Tds + vdp d ψ (T,v) = - sdT – pdv
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Unformatted text preview: dg(T, p) = - sdT + vdp Maxwell’s Relations: v s s p v T ∂ ∂-= ∂ ∂ T v v s T p ∂ ∂ = ∂ ∂ p s s v p T ∂ ∂ = ∂ ∂ T p p s T v ∂ ∂-= ∂ ∂ Fundamental Thermodynamic Functions: u=u(s,v) h=h(s,p) ψ = ψ (T,v) g=g(T,p)...
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This note was uploaded on 03/15/2010 for the course ENGRD 221 taught by Professor Staff during the Fall '08 term at Cornell University (Engineering School).

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Thermodynamic_Relations - dg(T, p) = - sdT + vdp...

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