HW9 KEY - Sessler CH310M/318M Homework Problem Set 9 310M...

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Sessler CH310M/318M Homework Problem Set 9 Due Wednesday Nov. 19 1 K E Y Please write the first three letters of your last name in the above boxes Name:_______________________________ UT EID:_____________________________ Signature:____________________________
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Sessler CH310M/318M Homework Problem Set 9 Due Wednesday Nov. 19 2 (Please include this page as page two in your homework set) S c o r e : ________ ___ __ ______
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Sessler CH310M/318M Homework Problem Set 9 Due Wednesday Nov. 19 3 1. Treatment of 4-chloro-1-butanol with one equivalent lithium diisopropylamide (LDA) as base leads to rapid formation of a compound with the molecular formula C 4 H 8 O. Propose a structure for this product and suggest a complete mechanism for its formation using proper “electron pushing” arrows.
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Sessler CH310M/318M Homework Problem Set 9 Due Wednesday Nov. 19 4 2. For the reaction of (R)-1-phenylpropan-2-yl 4-methylbenzenesulfonate 1 with potassium ethylthiolate (KSCH 2 CH 3 ): a.) Fill in the appropriate boxes (transition state, leaving group and product) b.) Indicate the stereochemistry of the product (R or S)
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This note was uploaded on 03/23/2010 for the course CH 54410 taught by Professor Sessler during the Spring '10 term at University of Texas.

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HW9 KEY - Sessler CH310M/318M Homework Problem Set 9 310M...

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