CH310-318 HW6 key

CH310-318 HW6 key - Due Wednesday Oct 22 5 2 Provide the...

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Sessler CH310M/318M Homework Problem Set 6 Due Wednesday Oct. 22 1 Circle the section in which you are enrolled: 310M 318 M 310M TIPS Please write the first three letters of your last name in the above boxes Name:_______________________________ UT EID:_____________________________ Signature:____________________________
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Sessler CH310M/318M Homework Problem Set 6 Due Wednesday Oct. 22 2 (please include this page as page two in your homework set) Score:_________
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Sessler CH310M/318M Homework Problem Set 6 Due Wednesday Oct. 22 3 1. Complete the following reactions using the boxes provided. These reactions may undergo rearrangements and may have multiple products. Where appropriate, indicate (by the use of dashes and wedges) the stereochemistry of any chiral center(s). (5 points each) H 2 SO 4 , H 2 O OH OH Δ + H 2 SO 4 , H 2 O Δ 1. BH 3 2. H 2 O 2 , NaOH OH OH
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Sessler CH310M/318M Homework Problem Set 6 Due Wednesday Oct. 22 4 1. (Continued) H 2 , Pd/C + HBr 1. O 3 2. (CH 3 ) 2 S O Br + Br Br + + O
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Sessler CH310M/318M Homework Problem Set 6
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Unformatted text preview: Due Wednesday Oct. 22 5 2. Provide the products of the following reactions. These reactions may have multiple products. Where appropriate, indicate (by the use of dashes and wedges) the stereochemistry of any chiral center(s). (24 points) H 2 , Pd/C HBr 1. O 3 2. (CH 3 ) 2 S Br 2 H 2 O, H 2 SO 4 1. BH 3 2. H 2 O 2 , NaOH Br Br Br Br + H HO H HO H Br H Br Br H H Br O O HO H H HO + + HO H H HO + Sessler CH310M/318M Homework Problem Set 6 Due Wednesday Oct. 22 6 3. Provide the mechanisms for the following reactions. Be sure to use curved arrows to show the flow of electrons and indicate stereochemistry where appropriate. a. (15 points) Hg(OAc) 2 H 2 O H H Hg(OAc) HO + H Hg(OAc) HO O O Hg O O H Hg(OAc) H Hg(OAc) + H (OAc) Hg H (OAc) Hg H O H H Hg(OAc) O H Hg(OAc) O H H H H O O + + Sessler CH310M/318M Homework Problem Set 6 Due Wednesday Oct. 22 7 3. (Continued) b. (15 points) H 2 SO 4 H 2 O OH S O O O O H H H H O H H O H H H O H...
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CH310-318 HW6 key - Due Wednesday Oct 22 5 2 Provide the...

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