mar_17 - 3/17/2010 Predict the product of the following...

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Unformatted text preview: 3/17/2010 Predict the product of the following reaction. OH H H H2O O H Predict the product of the following reaction. OH H H O H A B C D E A B C D E Predict the product of the following reaction. OH H H O H Predict the product of the following reaction. OH H H O H H OH H H OH C N H H H2O OH H H OH H H H C O N H A B C D E Predict the product of the following reaction. OH H H O H Predict Predict the product of the following reaction. OH H H O H D Cl H H O H H C O H O H H C O OH OH 1 3/17/2010 Predict the product of the following reaction. OH H H O H Predict the product of the following reaction. OH H H O H O H H3N O H H3N O O A B C Predict the product of the following reaction. OH H H O H Choose the order that has the following carbonyl groups correctly arranged with respect to increasing reactivity. Periodic Table Electronegativities O H H3N O O H3C C O CH3 H3C O C N H CH3 H3C O C S CH3 Choose the order that has the following carbonyl groups correctly arranged with respect to increasing acidity. O Biosynthesis of cholesterol. Periodic Table Electronegativities H H HO H O H3C C O CH3 H3C O C N H CH3 H3C O C S CH3 Χ O CoA S A strategy for drug development 2 3/17/2010 What is the mechanism of the following reaction? O O CoA S S thiolase CoA O O CoA + CoA-SH CoAS What carbonyl reactant would undergo an aldol reaction with 1 to give 2? O CoA S thiolase O O O H H S CoA A OH ? S O 1 S CoA + CoA-SH CoA- 3-hydroxy-3methylglutarylCoA synthetase (aldol reaction) + CoASH B C CoA 2 A B C What carbonyl reactant would undergo an aldol reaction with 1 to give 2? O CoA S thiolase O O S CoA + CoA-SH CoA- 3-hydroxy-3methylglutarylCoA synthetase + CoASH 3-hydroxy-3methylglutarylCoA reductase Lipitor H H HO H cholesterol 3 ...
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