03052010 - CH 310N MWF 8:00 Lecture 19 F 3/5/2010 Reading...

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CH 310N – MWF 8:00 – Lecture 19 – F 3/5/2010 Reading Assignment : 17.6, 17.7 Graded Homework : HW#10 deadline = 2:00 p.m. TODAY HW#11 deadline = 4:00 p.m. on Tu 3/9 Last Time : Mechanisms of keto-enol tautomerism Textbook Problems : 17.1, 17.7-17.13, 17.15-17.24 Today : Mechanism of the haloform reaction (continued…) Deuterium exchange and racemization at the alpha C atom of an aldehyde or ketone (end Chapter 16) Carboxylic acids (begin Chapter 17) PLEASE READ & UNDERSTAND SECTIONS 17.2 & 17.3 (nomenclature and physical properties) Spectroscopy Preparation of carboxylic acids
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KNOW THESE, PLUS BENZOIC ACID
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Spectroscopy IR : Let’s compare the IR spectra of butanoic acid to 1-butanol: CH 3 CH 2 CH 2 C OH O CH 3 CH 2 CH 2 CH 2 OH Strong C=O stretching absorption near 1710 cm –1 No C=O stretching absorption Very broad O–H stretching absorption between 2400–3600 cm –1 (obliterates C–
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This note was uploaded on 04/07/2010 for the course CH 310n taught by Professor Iverson during the Spring '08 term at University of Texas.

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03052010 - CH 310N MWF 8:00 Lecture 19 F 3/5/2010 Reading...

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