problem_set_xi

problem_set_xi - CHEM 302 Organic Chemistry I Problem Set...

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CHEM 302 Organic Chemistry I Problem Set XI Chapter 11 Introduction: The usual. Work on these on your own; consult with others if you need to do so, but realize that you ultimately are responsible for your own understanding of the material. Answers real soon. 1) Suggest reasonable ways to encouraging the formation of either CH 3 Cl or CCl 4 from methane in a photochemical chlorination reaction. 2) Sulfuryl chloride, SO 2 Cl 2 , is a commonly used reagent for the chlorination of alkanes. These reactions require the presence of a free-radical initiator, such as benzoyl peroxide or simply ultraviolet light. Suggest a mechanism for the monochlorination of neopentane in the presence of ultraviolet light by sulfuryl chloride. (show initiation and propagation steps only): + SO 2 Cl 2 h ! Cl 3) Give the expected product(s) for the following reactions. Be careful of both stereo- and regiochemistry: a) 2 eq. Br 2 h ! b)
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This note was uploaded on 04/09/2010 for the course CHEM 302 taught by Professor Myers during the Fall '09 term at Simons Rock.

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problem_set_xi - CHEM 302 Organic Chemistry I Problem Set...

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