L30S10_FreeEnergy_EquiK+04-07-10

L30S10_FreeEnergy_EquiK+04-07-10 -...

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Unformatted text preview: !"#$%&'(%)*+,%-./##%01#/23%415%6- Summary ©A.Pines,M.Kubinec,UCB )*+B& Summary Free Energy and Equilibrium 4%' G%>%A 4%' G%>%A C!%F + 6D& ?%! G%5%H ?%! G%5%H C! E + 6E& C!(%6 PJQ1R41#Q=; PJQ1R41#Q=; C! D + 6 F%& F%& C!E% MN%O1 6 ©A.Pines,M.Kubinec,UCB 6 E%#IJ BC% K% MN!L )*+B* 7'89:1#;(<86=>:1#?(@!A & !"#$%&'(%)*+,%-./##%01#/23%415%6- ChemQuiz7%30.1 T"4R%4/#% C! 415%6%UQ/ 4R%SX VSWKOL%%%%%VSWK2L 4R%SX!!Y 'L% C!D%+ D%+ 6 F%& F%& ©A.Pines,M.Kubinec,UCB AL% C!E%+ E%+ 6 D%& D%& !L% C!F%+ F%+ 6 D%& D%& )*+BZ Free Energy and Temperature BMNO1C! E% V! B N P! 6 O16%E B V! & G MN P! M 015Q 0IQ delta G* = -RTlnK O16 015Q 6 0IQ &\N ©A.Pines,M.Kubinec,UCB N )*+B[ Free Energy and Temperature C]%E% V]%BN% P] ]%B O16%E B V] & G MN :1R#/?#JR%E P! M B V! M P] M C! :1R#/?#JR%E V! ;OQJ#%E B P! O1%6 ;OQJ#%E N 015Q ©A.Pines,M.Kubinec,UCB 015Q )*+B^ &\N 7'89:1#;(<86=>:1#?(@!A S !"#$%&'(%)*+,%-./##%01#/23%415%6B V] & P] G O16%E LnK and Free Energy N% P] C]%E% V]%B ]%B M MN C] N V] P] V] P] V] P] V] P] O16 O16 GB BB &\N GG BG ©A.Pines,M.Kubinec,UCB )*+B_ ChemQuiz7%30.2 P"Q`1%:;%4%JOQR%QU%O16 P"Q`1%:;%4%JOQR%QU%O16 a; &\N% O16 O16 UQ/%b UQ/%bS%K;L bS%K2L8 T":?"%:;% R"#%?Q//#;JQ15:12%JOQR%UQ/% !WS K;L !WS K2L%Y &L% SL *L &\N ©A.Pines,M.Kubinec,UCB )*+Bc B V] & P] G O16%E LnK and Free Energy N% P] C]%E% V]%B ]%B M MN C] N V] P] V] P] V] P] V] P] O16 O16 GB BB &\N GG BG ©A.Pines,M.Kubinec,UCB )*+B&& 7'89:1#;(<86=>:1#?(@!A * !"#$%&'(%)*+,%-./##%01#/23%415%6- Free Free Energy and the Reaction Reaction Quotient CKM#4?R41R;L C%E%C C%E%CK9L d CKML C%D C%D + C%E C%E + C%F C%F + CK9/Q5=?R;L ©A.Pines,M.Kubinec,UCB eD6 eE6 eF6 C%E% f f G%MN%O1e CC%E% CCG%MN%O16 E%+ %E% C%E% )*+B&S ChemQuiz7%30.3 T"4R%4/#% C 415%6%%4R% #g=:O:>/:=$%4R%SX #g=:O:>/:=$%4R%SX!! UQ/ VSWKOL%%%%%VSWK2L Y 'L% C%D%+ %D%+ 6 F%& F%& ©A.Pines,M.Kubinec,UCB AL% C%E%+ %E%+ 6 D%& D%& !L% C%F%+ %F%+ 6 D%& D%& )*+B&* ChemQuiz© 30.4 hI:i T":?"%:;%R/=#%4R%R&Y '%K4gL G%S%A%K4gL G%S%A%K4gL !%K4gL R& R 'L%e 'L%e F 6 ©A.Pines,M.Kubinec,UCB AL%e AL%e E 6 !L%e%D !L%e%D 6 )*+B&X 7'89:1#;(<86=>:1#?(@!A Z !"#$%&'(%)*+,%-./##%01#/23%415%6- Lecture Complete ©A.Pines,M.Kubinec,UCB )*+B&^ 7'89:1#;(<86=>:1#?(@!A X ...
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