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Unformatted text preview: ' / {Egon 9(0) Sufi/\tflg‘fi’o TA‘ mronwfi Caiemm Maedmi IE'ZOPM Chemistry 2090 Written Homework #8 Please turn this homework into the boxes outside Baker 131 no Iater than 2pm on Tuesday, Novem- ber 24. Include both your own, and your lab TA’s name on your answer set. 1. ( a) The are and trans- isomers of Co(en)g (312 can be distinguished by reaction with the bidentate ligand, oxalate (0202—). What difference in reactivity would you expect between the two isomers? I Do; #0 H/wir dfi‘fi‘vmubin W "f4” ‘hi’iAnsei'jemw, {3 move Sivmbhk 49mm 3H“; as mom, Wig; 3*Ym5kf0v Shela idem ”fr; ‘H‘R +mm3' {59W 49 lmswfl Mdl'flgem ifliumcledw "3%qu anal ”Eh-Uri a?” ‘— barrow/L More Show»? ‘i‘flfm 03/ (30%" 5 ' Tm 0:3 “550 WU 3‘5 mew-a 735ml riwms (SW , \“CCUJKvfl )KV‘QV" (b) Is either of the isomers (as and trans) optically active (ie is not superposable on its mirror image)? If yes, which isomer(s) is(are) optically active? ”’16 hmsla'éomm (gnu; guprosoiole on its mirror image GMJ {g J‘Mwfigvfer 0191“ M HAIL. W CCSv {50W can {3% 5‘,pron Ov‘w it“) miwoi imp? a“); 1‘3 ”0+ Gloflxmflj (ALDEN/{,- 2. (a) The octahedral complex ion {IVEnChflE’~~ has more unpaired electron spins than does the octahedral complex ion [hin(CN)5]3“. How many unpaired electrons are found in each species? Bee gm (en-103m mfiimw 1m Lia mews. 5mm“ c, ' '0: — , n. Ed COMM” has erfi UDPMND} ehwmsioim a H“ V gm'wwh’ h“ 01:13 and twee we L" Upwixaol {LLU‘t‘fmraE'fi ’LEKL Q‘s JOU+ URL! 2 {PM {Km Cm 0:th ...
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