RelativeResourceManager - wavenumber / cm-1 Identify the...

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1 Final Exam Chem 205 Tuesday, April 27 th , 3:30pm 1/3 Thermodynamics 1/3 Kinetics 1/3 Spectroscopy
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3 Tutorials in D317:
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4 Practice: Notes with examples Problem sets Quizzes Old final exams: general VISTA page
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5 fomulasheet.pdf
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7 1.) Spectroscopy
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12 http://www.chemsoc.org/networks/learnnet/spectra/index.htm Practice: Problem Set 7 Old Final Exams
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13 O)H C( CH C C CH CH 2 2 3 = Sketch the expected 1 H NMR spectrum of this molecule. Clearly indicate which 1 H resonances belong to which group and include the splittings which arise from J-coupling, the expected integral for each group as well as the relative intensities of each line in the group Spectroscopy Example 1:
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15 Spectroscopy Example 2: Formula C 6 H 5 ClO Mass Spectrum Infrared spectrum m+ = 128 m+ = 130
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Unformatted text preview: wavenumber / cm-1 Identify the compound 16 } 1 H NMR: 13 C NMR: There are 4 peaks in the spectrum Integral=4 Integral=1 17 18 2.) Kinetics 19 20 21 22 23 (g) O 2 1 (g) 2NO (g) O N 2 2 5 2 + d c b a k k k k 3NO O N NO NO O NO NO NO O N NO NO NO NO O N 2 5 2 2 2 3 2 5 2 3 2 3 2 5 2 + + + + + + [ ] [ ] = 5 2 observed 5 2 O N dt O N d k The reaction has the following mechanism ( k are the rate constants), The reaction is a first order reaction with respect to N 2 O 5 Determine what k observed is in terms of k a , k b , k c , and k d only. Use the steady state approximation for NO 3 and for NO. Kinetics Example 1: 24 25 1.) Thermodynamics 26...
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This note was uploaded on 04/26/2010 for the course CHEM chem205 taught by Professor Unknown during the Spring '10 term at The University of British Columbia.

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RelativeResourceManager - wavenumber / cm-1 Identify the...

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