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Unformatted text preview: Alkane Alkane R(H) O Benzylic ketone or aldehyde H 2 , Pd/C R(H) (H 2 /Ni) Catalytic hydrogenation NO 2 NO 2 NH 2 NO 2 Selective NO 2 reduction Substrate Products Reducing Agents Name (Work-up, conditions and solvents are omitted) LiAlH 4 NaBH 4 (NH 4 ) 2 S OH O OH NR 2 O NR 2 OR O OH + ROH OR O H O Cl O OH Cl O H O Carboxylic Acid Primary Alcohol Amide Amine Ester Primary Alcohol Ester Aldehyde Acid Chloride Primary Alcohol Aldehyde (i-Bu) 2 AlH (DIBAH) LiAlH(t-BuO) 3 LiAlH(t-BuO) 3 DIBAH Cl O H O Aldehyde H 2 , Pd/BaSO 4 Rosenmund Reduction Substrate Products Reducing Agents Name (Work-up, conditions and solvents are omitted) Acid Chloride Acid Chloride LiAlH 4 LiAlH 4 LiAlH 4 LiAlH 4...
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This note was uploaded on 05/13/2010 for the course CHEM ORGANIC CH taught by Professor Dotsevisogah during the Spring '09 term at Cornell University (Engineering School).
- Spring '09