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CH151LectureSyllabusFall07

CH151LectureSyllabusFall07 - Organic Chemistry CHEM...

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Organic Chemistry: CHEM 151L.001: Fall 2007 Instructor: Holly L. Sebahar, Ph.D. Office: French Family Science Center (FFSC) 1225 Phone 660-1615; e-mail address: [email protected] Office hours: Wednesday and Thursday 2-3:30 pm or by appointment. Suggested Course Materials: 1. Loudon, G.M. Organic Chemistry, 4 th ed.; Oxford University Press: New York, 2002. 2. Loudon, G.M., Stowell, J.G. Study Guide and Solutions Manual to accompany Organic Chemistry , 4 th ed.; Oxford University Press: New York, 2002. 3. Molecular Modeling set - you can pick one up on your own or buy one for $25 Wed. 8/29 before class (LSRC) or 30 minutes before lab 9/3-9/14 (FFSC). 4. Goggles – for sale at the bookstore or in FFSC ($5) thirty minutes before lab 9/3-9/14. Class Meeting: Lecture: M, W, F 10:20 am -11:10 am. Room: LSRC B101 (Love Auditorium). Day Date Topic Chapter M 8/27 Syllabus and Alkanes – review basics 1-2.2 (review chapter 1 on your own) W 8/29 Alkanes – constitutional isomers 2.4,- 2.6 (2.8, 2.9 on your own; 2.7 later) F 8/31 Alkanes – conformational isomers 2.3 (bring ethane & butane to class) M 9/3 Cyclohexane 7.1-7.2 (bring cyclohexane to class) W 9/5 Cycloalkanes – conformational analysis 7.3, 7.4a,b (cyclohex. & 2 Me groups) F 9/7 Finish cycloalkanes, polycyclic compounds 7.5, 7.6a,b M 9/10 Introduction to mechanisms 3.1-3.3 W 9/12 Acid/base chemistry 3.4-3.6 F 9/14 Alkenes - Nomenclature, structure, properties 4.1-4.4 M 9/17 Alkenes – Relative stabilities, Addition of HX 4.5-4.7 W 9/19 Alkenes –Hammond’s Postulate 4.8 F 9/21 Alkenes – Reactions 4.9, 5.3 (5.2 on your own) M 9/24 Alkenes – Reactions 5.1, 5.4 W 9/26 Finish Alkenes, Intro synthesis in o-chem 5.5 (5.6-5.7 on your own), 10.11 F 9/28 EXAM I M 10/1 Stereochemistry - definitions 6.1 (bring your models!) W 10/3 Stereochemistry 6.2-6.5 F 10/5 Stereochemistry 6.6-6.11 (6.12 on your own) M 10/8 NO CLASS – HAPPY FALL BREAK W 10/10 Stereochemistry of Reactions 7.4c (skip 7.4d), 7.7-7.8 F 10/12 Stereochemistry of Reactions 7.9 M 10/15 Finish stereochem. of rxns, Intro ROH, ROR 7.9 continued, 8.1-8.5 W 10/17 Acid/base properties of ROH, RMgBr, RLi 8.6-8.8 F 10/19 Substitution and Elimination – S N 2 9.1-9.4 M 10/22 E2 9.5 W 10/24 S N 1 and E1, carbenes 9.6 – 9.8, 11.6b F 10/26 Reactions of ROH, RSH 10.1-10.4
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M 10/29 Reactions of ROH, RSH continued 10.5-10.8 (10.9 on your own) W 10/31 Finish Chapter 10 F 11/2 Exam II M 11/5 Synthesis of Epoxides and Ethers 11.1-11.2 W 11/7 Reactions of Epoxides and Ethers 11.3-11.4 F 11/9 Synthesis and Reactions of Glycols 11.5 (11.6-11.9 on your own) M 11/12 Strategies for Synthesis / Structure Elucidation 2.7, 4.3 W 11/14 IR 12.1-12.5 F 11/16 Mass Spectrometry 12.6 M 11/19 NMR – intro to theory 13.1-13.2 W 11/21 NO CLASS – HAPPY THANKSGIVING BREAK F 11/23 NO CLASS – HAPPY THANKSGIVING BREAK M 11/26 NMR 13.3 W 11/28 NMR 13.4 (13.5 briefly) F 11/30 NMR M 12/3 13 C NMR 13.6-13.10 W 12/5 Exam III F 12/7 Review Th 12/13 (2-5 pm ) FINAL EXAM Cumulative NOTICE: This schedule is subject to change. Together we will finalize the schedule at our first meeting.
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