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RecSet_5(152Lsum)

RecSet_5(152Lsum) - Cl Recitation Problem Set#5 CHEM 152L 3...

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Recitation Problem Set #5 CHEM 152L 1) p-fluoronitrobenzene is more reactive than p-chloronitrobenzene toward hydroxide ion. What does this tell you about the rate determining step of nucleophilic aromatic substitution? 2) The following tertiary alkyl bromides undergo an S N 1 reaction in aqueous acetone to form the corresponding tertiary alcohols. List the alkyl bromides in order of decreasing reactivity Br O Br SO 3 H Br O Br O Br
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Unformatted text preview: Cl Recitation Problem Set #5 CHEM 152L 3) Rank the following anilines in order of decreasing basicity: NH 2 H 3 CO NH 2 NH 2 O Br NH 2 4) Show how the following compounds could be synthesized from benzene: a) m-chlorobezenesulfonic acid b) benzyl alcohol c) 1-phenylpentane d) m-bromobenzoic acid 5) Which of the following compounds will react with HBr more rapidly? H 3 CO Recitation Problem Set #5 CHEM 152L...
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