Ch151PS10KEYF07

Ch151PS10KEYF07 - your reagents carefully so as to minimize...

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HO oxi aAr^rf Sct^s 1. Draw the structure of the major organic product for each of the following reactions. Mechanisms are not necbssary. If no reaction would occur write "NR." Show stereochemistry if approprrate. ./--,.-oH Nazcrzoz , 1 H2SO4, H2O lo Rotl U.il^**;f t/t lxon r cuD a J. kn" H,so, 5. )t-.-- CHs 20 Qu{ 2o Rot* 1. NaH/THF 2. CHsl gloeoisu'ns:s Se'm, Q'+ A/ ".-&t"'-.
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1. SOCI2 A_^, 2. Mgiether \/ v' ' 3. D2O 6. 8. i.e/-on ""' A-B.r CrO 3. 2 pyridi ne/CH2Cl2 g. distill Products rlf' J 1.NaH 10. -tt + 0 -S-OCtl* tl 5 o |/t/lht,r mln0r L) -T-
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CHM l-5 I t..001 ; Problem Set 8 2 Propose a synthesis of the following molecule by the Williamson Ether Synthesis. Assume
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Unformatted text preview: your reagents carefully so as to minimize formation of by-products.-'--r^o"\"'\ (, ./L C^o1'1 3 Design a synthesis of the following molecule. Note: this synthesis requires more than one step. (^)< (Y a . L J O H \ J D I CHM l5lL.00l ; Problem Set 8 4 Provide reagents that would lead to the highest percentage of the following products. r Propose a mechanism fol the following-transformatiotts a **p *Tg-P%t[ 15 H3P04 o testosterone noF,t a bo* Naorf 0r 0v{ Ef-t- C-skelc#., u{err Vr'"{9 J+ CHM l -5 I L.001 : Problem Set 8 u Hzo ^s-^--<oH + HCI L . \ / cat. H+ ,T-N ..-Hro +cP--,) a-t H3a{-u * D* {-! b...
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This note was uploaded on 05/13/2010 for the course CHEM 151L taught by Professor Roy,christopher during the Fall '08 term at Duke.

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Ch151PS10KEYF07 - your reagents carefully so as to minimize...

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