Chapter5-8OutlineF07

Chapter5-8OutlineF07 - Chapter 5 Alkene addition reactions:...

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Chapter 5 Alkene addition reactions: HBr HBr/peroxides Br2 X2/H2O 1. BH3 2.* H2O2/NaOH 1. Hg(OAc)2/H2O 2. * NaBH4, NaOH **For all of above: o Understand and be able to reproduce mechanism (accept* H2O2 oxidation of R3B and *reduction of RHgOAc). o Predict major organic products o Predict correct regioselectivity o Predict stereochemistry of reaction o ID relationship of stereoisomers, determine product distributions (equal, unequal) and whether or not product mixture is expected to be optically active Ozonolysis: Predict products based on different work up conditions (oxidative vs reductive) Predict SM alkene based on products Do not worry about mechanism to ozonide Chapter 6 Differentiate between stereoisomers, conformational isomers, consitutional isomers ID enantiomers, diastereomers, meso, identical molecule based on molecule shown with tetrahedral carbons (dashes/wedges), Fischer projections, chair conformations, Newman projections Assign R,S on acyclic and cylic systems
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This note was uploaded on 05/13/2010 for the course CHEM 151L taught by Professor Roy,christopher during the Fall '08 term at Duke.

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Chapter5-8OutlineF07 - Chapter 5 Alkene addition reactions:...

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