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Chapter10OutlineF07 - Identify constitutionally equivalent...

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CH 3 OH methyl alcohol primary alcohol OH OH OH H 3 C CH 3 CH 3 secondary alcohol tertiary alcohol H 2 SO 4 or H 3 PO 4 heat HBr or HCl or HI Cl S O O CH 3 pyridine NaH or KH SOCl 2 , py PBr 3 Na 2 Cr 2 O 7 , H 2 SO 4 H 2 O CrO 3 2 py (mechanism) (mechanism) (mechanism) Na or K metal (mechanism) (mechanism) (mechanism after chromate ester formation) (mechanism after chromate ester formation) NO mechanism NO mechanism
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Chapter 10: Predict products of all above reactions including stereochemistry. Know all mechanisms except formation of the sulfonate esters, formation of the chromate ester and formation of an alkoxide ion with sodium or potassium metal.
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Unformatted text preview: Identify constitutionally equivalent and non-equivalent hydrogens. ID homotopic, enantiotopic, diastereotopic hydrogens. Understand the difference in reactivity of each with achiral and chiral reagents (and soon chemical shift). Be prepared to use the above reactions in 1-5 step syntheses. Identify a process as an oxidation or reduction, identify an oxidizing agent or reducing agent. Predict the general reactivity of the following types of molecules and explain why. O S O O O R R R = H or alkyl group , R O R R...
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