Final Coverage - Final coverage Chem 1570 Spring 2010...

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Final coverage – Chem 1570 – Spring 2010 Reactions - Synthesis 1. oxidation/reduction 2. alkene addition 3. S N 1 and S N 2 substitution 4. elimination 5. electrophilic aromatic substitution 6. nucleophilic addition 7. nucleophilic acyl substitution 8. enolate ion reactions a. aldol reaction b. Claisen condensation Stereochemistry 1. R,S and E,Z and D,L designation 2. chiral and achiral, stereocenters 3. enantiomers, diastereomenrs, meso structures Mechanisms 1. alkene addition 2. phenol anion, electrophilic aromatic substitution (resonance) 3. nucleophilic substitution (S N 1 and S N 2) 4. elimination (E 1 and E 2 ) 5. SOCl 2 with alcohol and carboxylic acid 6. Williamson ether synthesis 7. nucleophilic addition 8. nucleophilic acyl substitution 9. enolate ion reaction a. keto-enol tautomerism b. aldol reaction c. Claisen d. decarboxylation 10. mutarotation Physical and chemical properties 1. energy diagrams, conformations 2. how to separate compounds 3. identify polar/apolar and hydrophobic/hydrophilic regions
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This note was uploaded on 05/15/2010 for the course CHEMISTRY 1570 taught by Professor Walcot during the Spring '10 term at Cornell University (Engineering School).

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Final Coverage - Final coverage Chem 1570 Spring 2010...

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