AlcoholPhenolReview

AlcoholPhenolReview - 2-nitrophenol OH NO 2 4-nitrophenol and Reaction Conditions Substitution Products Reactant Phenol Benzene Phenol Benzene Br 2

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C 2 H 5 OH Ethanol Oxidation Cr 2 O 7 -2 / H + aq CH 3 COOH Ethanoic Acid CH 3 CHO Ethanal Na C 2 H 5 OBNa Sodium Ethoxide Fermentation Sugar/Starch NaBH 4 aq Hydrogenation CH 3 CHO Ethanal Aq Dilute OH - Alkali C 2 H 5 X Halogenoalkane H + /OH - Heat CH 3 COOC 2 H 5 Ethyl Ethanoate Hydrolysis H 2 O CH 3 CH 2 OSO 3 H H 2 SO 4 /~80˚ C CH 2 =CH 2 Ethene Cracking: Petroleum Natural Gas HX Br 2 Add n H 2 MnO 4 - /H + H 2 SO 4 Excess C 2 H 5 OH <140˚C C 2 H 5 OC 2 H 5 Ethoxyethene H 2 SO 4 Excess Acid >140˚C (or H 3 PO 4 ) Elimination CH 2 =CH 2 Ethene PCl 5 C 2 H 5 Cl CH 3 COOH Conc. H 2 SO 4 / Warm CH 3 COOC 2 H 5 Ethyl Ethanoate Esterification
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OH Phenol Br 2(aq) OH Br Br Br 2,4,6-tribromophenol NaOH (aq) O - Na + Sodium Phenoxide Na O - Na + Sodium Phenoxide CH 3 COCl O – C – CH 3 O Phenyl Ethanoate HNO 3(aq) Conc. OH O 2 N NO 2 NO 2 2,4,6-trinitrophenol HNO 3(aq) Dilute OH NO 2
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Unformatted text preview: 2-nitrophenol OH NO 2 4-nitrophenol and Reaction Conditions Substitution Products Reactant Phenol Benzene Phenol Benzene Br 2 • Aqueous • Cold • Room Temperatur e • Liquid Br 2 • FeBr 3 Catalyst Br Dilute HNO 3 • Room Temperatur e • No reaction Conc. HNO 3 • Room Temperatur e • Concentrated H 2 SO 4 • Heat <60˚C NO 2 NO 2 NO 2 Nitro 1,3-dinitro benzene benzene OH Br Br Br 2,4,6-tribromophenol OH NO 2 2-nitrophenol OH NO 2 4-nitrophenol OH O 2 N NO 2 NO 2 2,4,6-trinitrophenol...
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This note was uploaded on 05/23/2010 for the course IB 1503 taught by Professor Slone during the Spring '10 term at Gwynedd-Mercy.

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AlcoholPhenolReview - 2-nitrophenol OH NO 2 4-nitrophenol and Reaction Conditions Substitution Products Reactant Phenol Benzene Phenol Benzene Br 2

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