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Rev25 - Chapter 25 Review/Practice Problems 1 Nomenclature...

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Chapter 25 Review/Practice Problems 1. Nomenclature. Draw structures for the following: Ethyldiisopropylamine Pyridine hydrochloride N-Methylaniline N-ethyl-2-phenylpentamine 2-(N-methylamino)butane Tetraethylammonium bromide Imidazole Pyrrole 2. Acid-Base properties Arrange the following sets of compounds in the order of decreasing basicity. Given the following pKa of the conjugate acid of the amines, which is the strongest base? Also draw structure of the conjugate acid. (Find structure from your book if you're not sure.) Pyridine 5.16 Imidazole 6.9 Piperidine 11.12 Describe how you could separate a mixture of benzoic acid, benzamide, and benzylamine (draw their structure first) using solvent extraction. NH 2 NH 2 O 2 N NH 2 A B C NH NH 2 A B C (a) (b) NH 2
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