Chapter 22 in Class Problems Solutions

Chapter 22 in Class Problems Solutions - 2 O HNO 3 /H 2 SO...

Info iconThis preview shows pages 1–11. Sign up to view the full content.

View Full Document Right Arrow Icon
6/13/10 OH 22-1. Synthesis 5/ 1 0 OH Cl O AlCl 3 O 1. LiAlH 4 2. H 3 O +
Background image of page 1

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
6/13/10 22-2. Synthesis 6/ 1 0 Br 2 , FeBr 3 Br Br + separate Mg, THF MgBr 1. 2. H 3 O + O OH H 2 SO 4
Background image of page 2
6/13/10 22-3. Synthesis 6/ 1 0 Cl O AlCl 3 O NH 2 NH 2 , KOH NBS Br K + OtBu -
Background image of page 3

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
6/13/10 O OEt 22-4. Synthesis 6/ 1 0 Cl O AlCl 3 O O Zn/Hg/HCl/H 2 O COOH OEt EtOH O Cl SOCl 2 1. KMnO 4 /OH - /boil 2. H 3 O +
Background image of page 4
6/13/10 22-5. Synthesis 7/ 1 0 COOH Cl O AlCl 3 O Zn/Hg/HCl/H 2 O NBS Br Mg, THF MgBr 1. CO 2 2. H 3 O + COOH
Background image of page 5

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
6/13/10 O NH 22-6. Synthesis 7/ 1 0 O NH 1. KMnO 4 /OH - /boil 2. H 3 O + COOH HNO 3 /H 2 SO 4 CO 2 H NO 2 H 2 /Pd/C (does not reduce COOH) CO 2 H NH 2 SOCl 2 COCl NH 2
Background image of page 6
6/13/10 Br NO 2 Cl 22-7. Synthesis 5/ 1 0 Br 2 , FeBr 3 separate Br HNO 3 /H 2 SO 4 Br O 2 N Br NO 2 + Br NO 2 Cl Cl 2 , AlCl 3
Background image of page 7

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
6/13/10 NO 2 Br 22-8. Synthesis 5/ 1 0 Cl O AlCl 3 O Zn/Hg/HCl/H
Background image of page 8
Background image of page 9

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
Background image of page 10
Background image of page 11
This is the end of the preview. Sign up to access the rest of the document.

Unformatted text preview: 2 O HNO 3 /H 2 SO 4 O 2 N (separate isomers) NBS, hv Br O 2 N 6/13/10 HO 3 S 22-9. Synthesis 5/ 1 Cl O AlCl 3 O Zn/Hg/HCl/H 2 O SO 3 /H 2 SO 4 O SO 3 H SO 3 H 6/13/10 COOH O 2 N Br 22-10. Synthesis 5/ 1 1. KMnO 4 , heat 2. H 3 O + COOH HNO 3 /H 2 SO 4 COOH NO 2 FeBr 3 , Br 2 COOH NO 2 Br 6/13/10 NO 2 22-11. Synthesis 7/ 1 Cl O AlCl 3 O HNO 3 /H 2 SO 4 O NO 2 NO 2 Zn/Hg/HCl/H 2 O...
View Full Document

Page1 / 11

Chapter 22 in Class Problems Solutions - 2 O HNO 3 /H 2 SO...

This preview shows document pages 1 - 11. Sign up to view the full document.

View Full Document Right Arrow Icon
Ask a homework question - tutors are online