Lecture5 - L5. IRAN“, 2,1010 gammday! @319cw 2.010 IoPAc...

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Unformatted text preview: L5. IRAN“, 2,1010 gammday! @319cw 2.010 IoPAc KULES 0F MOMEMMTuaE 1.; ALKANE‘S 3 p 3 k F\ 1 Liz? Subumm # o <._ QMA ‘ [Marduk 0550M! M I, 0 “ms”? chain AME Erw‘ av. [Muzak cox/\vaous Gina?“ 0} Cargo“ «Jaw LVN-1J3 WW1. ~Por 8C: OC'T) new» L3 6% Surf’fx AME ($4, a” aflKam) rows atrac‘nui to Hm. Main data are swarm catch HAW MA mmeM CM (’43me aka)» «than :30 a}: HM. P/wA wrex ax Sulskdflemt “I c. alum s EH3 But «by! at - cu ~CHL 3 l ._ CHI-CH3 7 c mm 4 It,“ “SfH— CHI-CH3 «A H 104 ~04; M 5&3:th c 3 1 CH3 \ 16H3. 2) Write. UM. RAIN arranat‘nj ( NULMLLV' 0.5 Skowa) SuLCZlL’ue/NO Ljvx arm. U81 HM; (\Ao‘fx AL, bui, 5.11m, pow-5x [To (Award: M42. SULLXCCAMS a} ding $1M fifpe. - l Netti P «‘1 ’} 1/4/S‘busmd'ix7/ 941/ CR, tic.-. S’ .. m MV' unhhrd wkm arranan 3 - d'L‘Y' k9 451pka .qu Co U» “Mac :5 = 3—etlxyl-1,4,S-t'rimd‘ky"\epfam ’PHisicAL maven—{Es 0F ALKAMEJ Mamas are. non—PJaw mokmhf HAM &t‘SSOIVC [\A nonvpolaw' ov low polan‘C'y SolVevsz. "Lime 'DfSSoLVES UK:“ \/I an kngroekoLfc awd 4.0 not” M3501“ .‘y‘ w (Ur. 61:13 03,003 ‘ULV‘:¢4'\t-S OUAA pchert/‘aaxleg r metals ()reMevJG‘nJ cow-os'fovx Water 300 densitz o} alkawmj m 9. is Mr 07 ML 200 - 0-75 C} 3/ 0 Density ' / g 2!: WV (ii/Lam wax-CV E 100 f / g *3 / Bmhng :Jom (1 INN”) “g 0 f 0.65; a’ . . g 01‘ 4(0me 01A Wafér P400 - Memngpo'“ g 3 7200 0.55 J“ a ‘ 1 2 3 4 5 6 7 8 9 10 11 12 BOlll“:§ Numberofcarbons(n) Kath tncfeASeI widn Hm. :H 0L C (1%an (aLowt’ [m whom WP to cm owl awa lo'c ,MA can.“ Bo Clo) LP cl LraWc‘neJ ail/Came: 1's ohm/av than (144!“ 0‘ “Mar 4Q,va (Am aka’ London Swans) M Pot/Rt (m p) ColNFomn-r'icws oF ALKANEIS "Wu. grad: arranabmws ck otde 42°er Nora/{75w ed» A. Swab. 100M aurc. Calla! Cemewmaxuks. A Artusz Co rmak'dm Es tern/v.4 a\ “ConFokMErU . In ohm/Wm! Com.‘ rmus Comm}- LI. {Solat'd Lcwuux HM. wwch cure. n» in; oom‘amdy meJk all P°S£{LL<H awfwmakoo'ks 55453ch M4oimalrwk 54 433% L an C-H Lon—35 on A’MVL‘KW {A {My BMW {0" “({9st aux‘ormarwzq é (mulch; Mko \owcv- may Fr shajud. NOTE . You MULSV learan Mo‘ewlaur modal: Yo fist/alum. orxam‘c molmlbs 0.“! experiment 9.15% clumsu in adumdaa“. 2&1; Sc) (35 vnALf'{S hi VUUf uh.QJuA,7 LM (JAWDQ-vfé: Cam‘ormer 3M, (LL-«J:- km! mutt." . “M Rm attach?)ch o+w M 3 amps?“ Mt’emd'dns 6n mud. on H W .mutkur. anL “a. H-“ mglwéj ' fimwfi Bo N l MM“ Ea=29 kcal mol" _ _ _ _ _ i _ _ _ _ _ H H H H H H H H H H H H H H H H H H H H 0 60 120 240 300 360 TorsionaI angle 3 . (Mama Lo Lowest MK energy As: gamut ‘. AMA aLout an. angormqfis‘ns .1, prepay. u'vx HM. 500K, aLaLpt'al . 'Do aunt‘s“! 180 {6‘ W‘ W CDKSi'J-ILV' Conformation: 0. {Sing {ram Mrs.th «Loaf all C~C (mud: , 1 ~ mst inttQSKn) at; I SQ, ‘7‘,th C; at Bunk-1N CH 3H “ ' u A x “ H CH3 H Ana Confirm H “‘3 H (‘14; H (eowqc'cmrfl) Anti Gauche Gauche E32 = 4.0 kcal mol—1 £a3= 2.? kcal £31: 3.6 kcal _] mol mol '1 H H 0W H C H3 H C “Fulfiom‘ gauche 0 60 120 "ISO 240 300 3 Torsional angle swam; (in would“: ruckense HM. enema)! a). a Spcafx‘c. Coqme a, & Numb. .Flw'xb hula? My akaxc, FBV‘ Lwrauu. 0s M{n?mwlx u'n may 1'; MAM wlwn HM 2 md‘fvull 311mg; 9‘. c4 “A C4 cure u...” ,“b 0" u \n 0"»:th Steins: Q—cmg % “bf 53 M964? "’7 \H u H CH: CH: Th Lg um um“ WWW” :4 mm W" Mde] l‘uups white. “AA oduA I c. a"; I Kai/ml H: H ~14 chpfino A“ H-H edxpgenj 1 Kai/“L H duh—ms cck'psu‘mj a! 2.7 ($3 aural] may £{fitmu I.me tlu. Lest (Mam, we 4»: tan“ '04 ml, 5 Kat MM H Skid n vixen are.“ aura-I; "23‘ch 2.7 (‘1‘ "J3 Syru‘n CHs-CH) Shh c o . 3 War with math): to “Sn.- Nwmq Profcfioks .Fr Lula“! [04 (Can MALI-4 “gonad dissodaL—wh may“ or 338' -——> H- -H AH°3+Io4 Km! wk.“ / THBLE 3-2 Hand-Dissociation Energies for Some Hlkanes \ DH" DHu Compound [kcal mol"} Compound [kcal mol") CHfi—H 105 CH3+CHJ 90 C2H5+H 101 C2H5+CH3 39 C3H7+H 101 CzHS-P—CzI-IS 88 ((Tllj]2(‘.E-IC}{2+H IO] (CI-192C.H-e-CHj 88 (CHshCH-E—H 98.5 (CH3}JC—E—CH3 37 (CH3]3C+H 96.5 (CH3}2CH+CH{CH3}2 35.5 (GHQJC-fi—CHIHQJ m5 Wm.- See footnote for Table 3— L j 0‘ 0\ 50M : pious: a; Lord Lfcadfvinj \Niok wk Agroflmcnk' numb/<4 om darn/"on {gram/\de enemy vim/ele wk film‘s Pmcau '6: HM. Lad discocem.“ 5(— FE) exclamch demfauae. a; (TLV. C—C. Loud MK exfaawu Pr W 5.00 -C.H-5 (Moth/l) Meals arm"¢os(7“ at. +30 K641 MW‘L—4 912% __> H30 + was AH2+30 mama" "’6 CB MM A C‘H loud (JIA mefkaunc. quag+t04 Kai mic", C. Low! and Cx-H Lev/1.5.4 Can Lc H C—CH‘L 1-130an + .H 1: a ' . . ° " H1 9,1171 m! M = +101 Kai mot» THHLE H Band-Dissociation Energies of Uariuus H—B Hands WP in kcal mnl‘ll B in A—B A 1n A—B —H —F —Cl —Br —1 —0H —NHz H— 104 136 103 87 71 119 108 CH3— 105 1 10 85 70 5'? 93 84 CHJCHZ— 101 1 1 1 84 70 56 94 85 CHJCHZCHz— 101 1 10 85 70 56 92 84 (CH3)2CH— 98.5 1 1 1 84 71 56 96 86 (CH3)3C— 96.5 1 10 85 71 55 96 85 Nam: These numbers are being revised continually because of improved methods for their measurement. Some of the values given here may be in (small) error. H. gown Law/J: Him} aft, pavfitmburly MIMIC ¥reqMLnHy (Fm/011k) va LeovayCCc CWW M20511 Fur xmpbz, 0—0 or cl—J» Lanai! -0-O—CH3 —* l (fl-(30' AHO: KM MOLL‘( %,L\r Mw‘n ( Zr A1710 Co QXOHAUNH‘CI chamch cure. Co T‘sz CAM 19¢. 40W [Hula Wad." AG" will Le. W1 ‘°) comuJOuLA HBr Amudm M to I pre, awe 1 ~ Eromoddfi‘km- CH3 C1413" CH3CH1-OH + H—‘Br —— CH3CHL—‘Br + HvoH Louis to LL Lr‘oKbvx L‘m'd‘ {6° (’9 "MAI. Cfist—ou H-‘ng cu3cuz—«gr H—OH +34 +87 ——‘70 —ng E ’07 +94 +87 away —7o-—ug + (8‘ KM1 Moll:( WNLL—l K—W OVerail Audio?» M": +m 483:. —8 mmali‘ 'TLLL creek {4 eiodaefmh! Since. mm win Lc. J‘wxa.” a“, Magma k may to WWW. ms:|y_ L 2"“ cm c. I: no chatty; V5\ anal-1f «A Z mums almolpwlbi {finmenl’ : a ckapbr 1, Ac guru‘s“ cud proUws Wb‘nwc— SW dumpt'er 3 ...
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This note was uploaded on 06/28/2010 for the course CHEM Chemistry taught by Professor Nitche during the Spring '08 term at Berkeley.

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Lecture5 - L5. IRAN“, 2,1010 gammday! @319cw 2.010 IoPAc...

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