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Lecture7 - '0er CH Lug-VI(9.41 H mm «1-4 M H “.mt v....

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Unformatted text preview: '0er CH Lug-VI. (9.41 H mm «1-4 M H “ .mt , v .» \ bond-s —tozKu1mh.“ WM" . tall AH°= +Io4+fl-8(-l03=-2:|QA”L:I 2.10 ‘c mm... “3 «cuevsyg “w, ”W 'i AM 90“ cchC-na ’o (om , Mk con Uvufovcs M’ P 5 r: 9 1m to. (on v; # v/ # ,.' -’ no. .' ( V. 0'“. d“ I r: “IIJW- — -/-- 0'— vc‘ I I Cost +l05 (€84 " ‘ ’ mo. 00cm“ CNS S 6. ”LI“?! undodwrmi'c A-O— awn" N ‘3. A n n JI-s - —~ 3 - - COSB+SK ”mo» 6% r . _ 'I. u ' kc AHO = - 27 Ku‘ Mb." ! we. unshtw Lotk . U; . . 4;ka 4 —’ [A L g ‘A ¢A A A - _ - ‘ a A“ K 1 0 ~ , " '7 LMAAA on . run) ' If: prong " cam» A - , cm AM w" o cflmnAun M you: VI ennui-.1 [wow luau-cw. thmd‘wk (Lu. “Vac.” “OHJCI . It “0 CID-h www. C2150 PM Cflzdz, 04:13 and #:Mlly Cceq . fir cimlak: H H d’é'viflad a—9 d—éO + H4 [4 H ‘d-CI—h-d ‘1— J- A‘Iclnlofowex‘aan CHLJL .0. W cam paw 6934-1, (2(4de ’ fit—ids «A we;( all .1 Ch”. coal“ '1,“ L3 Afsallatién 0.3 (13.7 M‘ Veg-7 Jaw Lama pu‘nt’s. l-lo cm , MMJBR t. 44» c1434 apnea“ ‘ C _ ’ {4 UN. 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H- mm mm cu -_ ”Na ca‘list‘on [ca-ls to T51 Hum to UN. fifmeXAL'a-h and {4—61 . N “on oF Hts-ask ALKA : 13‘ “n a c ELECT; \- SwwLou-y C. C! 0+) A A A ‘ MA ‘ D ' - _ 7 w I / ‘ V' I— - L A'i - A , ’AV 3 ( \ «Kat C. ELL-h 00:13de W Caucurr H “W c" L—H Louis our, wow Marx/t. “ tuSCL‘aryH I‘m tonal L9 magma-K. .ym BM '1)? Scam-«M! Ewen-t6: 2 ‘ 04 F" o J‘ a v' m. 7.'" Ho acuuminm-Iou or: 2,- Merkylpropame. CH —c.—H ———> CHs-C‘r’d ws-f-H CH3 ' “h v— I.” u. ' ‘Muqu—tr ‘ g. ; 4° 5 ; SUM.” we, wouJLJ expul' lo'/oA W 30% 13 AW“). Hum (A!) UAryH our°10 ”HMS , WryHJ '0 a. A ”I 0 ‘ m ~ , ~' ‘ ‘ -- -. ' to 1.6.. ' v- ', l.- “pr . nrw P") __ (Ban) 'DISSockt-‘M A ‘ 0- I ‘ bum-as] "' ' U': c z-cH—u-l “M?- A ‘ = 4. u’ H g A o‘- u I _ “I l- “P L F n mac—'Hud CthMY 9“,! “4“ Or 033...“. -' M H . ma“: ‘MJYI' 02.4 [min ~~M 'vv u. um. ,n ”Wm ' m 9H ' 1 A AAA“ 1 Q. '6 0d"°("‘ “i‘ d ”;I‘ l CH H CH -—-5> CH ~a4-u4 - -a.’ ‘ (9 J. , I g Q *0 1 D QM 4-164 Pfimod‘y H', c “CHL' 3 TC“, yfimory owul Setovulcuy H‘. 7‘ 'AQA HM. Saw MAcXLx/ij We. “on . H ’ 7 °/; 0 Lu}: 1»quer H‘. M WM IMCXIJL! I W: Vs] 6 and"). H5 . : N ‘ r , w _ . __ 7 . _ / . L I‘ ova {LA LL : Midis/e. mama :« cHon‘nafiM—S !. .,., ' « MW: a (2-H Lord: in I 1-- raAzc-AJ Hum. no tch‘our C44 9 ° ° Luck are CL». aura, Mov‘e MAcXLm A f A u ‘ f ‘ i! ' f v . l _ 4 } - _ . _ .- \ f o " ' ' F a. JP.» ’EPcb CHAPTER 2 mu: ’ 0 em“ 0 “Lulu: c‘nJuuLtn dun ta ta? are-3. m a (pan? «amt-ta {m- to . STAfil-PTY 0F F166 «menu ”*7 M 'No - Title I“ ”raw 0.“ can four encr me 5 wm ’ or ‘ um a. -nc—naAL J . .r am .A ‘Mar ~ ”M. v- ‘ I cert- ‘ r ‘— “A; wb ‘ . klflfik T:VV\T IAL‘ 1” oAf‘ ml eat «ode - ‘z —¢.H— -f-" ' l -__ 9" -__' I P -CH1 -CH-' —¢-—- '5 H H H on .. .. =~. ffina ‘ co J . 'Tefl't'a q¢wp div. C—H 130M: VIA med/~04“, cure Wen SK/om’u I‘ vthkfl Meal - CH3 'v; we.“ Luigkur vcx mar-57 Hunt 5 . .b. . 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L-‘I' {A t ' OUR/3 , ' ul “.1 Mao “ L); “ u 4 H74. tin/‘2‘. ‘ lALmrivx At- waox ovul -— A ”Ar Mal call/u»; lower gm m r F412. ' - | Monokominarwk 3% Albums . m C 3-CHz~C}L—\3 + Brz 77> CH3-CHL~CIZHL +CH3—fH-CH3 I r 5 h I ' ‘ ‘I ‘ 6 l o z 4 ‘ A . . A v, '7' v - "v' v 7", v ‘ , ‘- [9 'aum/ 3.6..11- CH :7 O.(% ,MAH CW1“ 5.41, «r 1H =>»4e'/a H l I I 1' Sachem"?! H4 W ——: 0 V 04 a“ l \g i ’I ‘- ‘ I3 In} (3 ("”3 l v 9 o ‘ 0 o " ‘H/eJ/‘QII: .romfnafwk t}: {MAM—CA mm ”dewa/c au‘ CHOV:V\AI00‘V\ Luf also WALL nut/ctr Lcm (XII? 'r'o a’o 7491K S‘hr «“5 Very QACLOL ermf‘c, ‘WM‘R (11¢. [MAO/LA «1105‘ «554% mm! szmt'i AH" Fl orinai’fon : a. Mazda we‘d‘ with Se‘wfivvg {fiat "award“ 8%,. «5» {W to Wkly a me. www.}mH-Few, trustee.“ 5m. :. ma early ml w. 67.»: 4 ~— 13: KCA.‘ mob”! _. —3§ LC“! mt.“ THBLE 3-5 Relative Reactivities ef the Four Types of fllkane E—H Bends in Haleqenatinns F- Cl' Br' 0—}! bond (25°C, gas) (25”C, gas) D :3 ate K _L\ 21 (-T "E i E‘ $q '3' 7 \ 1 RzCH—H l .2 4 80 RSC—H l .4 5 1700 THBLE 3_5 Enthalpies ef the Propagation Steps in the Haleqenation of Methane [kcal mill—‘1 F Cl Br I =:)§'+CH4 —> -CH3+H:):(: —31 +2 +18 +34 -CH3 + X2 —> (21433: +=§§- —72 —27 —24 "N K“ 1L. Amer team 4 MM week 11:; me- 7.“th ! ...
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