chem3B-Fall07-mt2-Viernes-exam

chem3B-Fall07-mt2-Viernes-exam - [J H {12 [115} a Pnnide...

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Unformatted text preview: [J H {12 [115} a Pnnide nomenclature ur' slructurts fur the following: J Tnfluoroacetlc acid Methylpropylamme N.N- Dimethylmrmamsde {EMF} '.-J I; {[3 {ma} Fill in the boxes. Om- comfluund [Jr reaction_:§£ep per hux. Indicate slerenchemistn when necesrznnu | I“? I _. ‘ _ | .-. DCHt — IR 3” ' KT Q 21H - H20 | OH in J a “M '“w” I in l ' I i - / Jam CH OH ‘ ’ f—i | ‘ El “ I I _ m _ | \u. ,0 ’ ’ ' ‘ \f 3‘ , Ffivmxfix’ 3' “e- 9 o Jr LL'rU 9L4} t'nmplrtr the follmring l'nadmap. 011:: compound or reaction step [101' box. . —I ' ‘ : I -' II I _ .9" ' - O a. ,H,‘ ,zuHu —-- ——‘—- ,_ fl - - ' I. fly HT. w I, Kw, I T, NHE O f 2] H*.-' H20 .V,‘ .H HgO NaOH u: \l H " ' IIIII I _ _ _ _ _ ml .‘r: J .v ' we? RV,» a 55/ .J. 4} {H [11.5) 'Prmidr [he prmiucIL for {be following transformation}. / _.—-I' ‘ _l _'__4 ___ \ Thermodynamic; Product f. Why is: yuur compound [hL' lhummdynflmiu product? Answer slmuld he phrased in any stalling-e, 5} 13 pt5i Predict the product of the reaction. hr affixl —I-- I ' i (.fircle the direction of the ring closure Conrotary' .1. Disrotary /L_ Provide the molecular orbital depletion of the molecule to rationalize why your product rotates in the can- or disrulary direction. Use the structure below. Clearly draw in the methyl and ethyl groups and the HOMO andfor Hill-10. {1'} {ill phi; ' l’rm uh:- a mechanism for 11h:- t'ulluwiug Iranst‘urnmlimI. o 23' .|. i“ .. : EICIH . ‘ ~ [II-I |.__" I L,_': I '-. I I I I T} [24 pm ' Provide :1 Inuuhanimn for tln: i'flllu‘u ing transformation. I.) NaOL—Tt EtDH a . l | 0 1L - - 'OEr l :- U 3!: mum-J l’rmiclc tlu' L193] 5}"ii1ltltL'I'fHJEi‘Itltl1frliliiJ11-‘iflg mnlu'lIE—r. I _I j _ _ I Izmir, KL EL“ and ar-=-,rc:herg73r1:r.g maier-als '12?" "“ Etil' 0E3 Eca'hens or 555 1H 9} [215' pm} ' I I ' I l’rm'ldu the best H}'l‘llhl‘:l1l: mute tn the {allow-ma mulm‘ule. I From and EH3: other starting mmenazs 9““ N -’"‘-- , ""‘K 8 carbons or less Light musLbE ' H ,0 aged in one ofyour 3:995; : an x"- f I. J. ...
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chem3B-Fall07-mt2-Viernes-exam - [J H {12 [115} a Pnnide...

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