Kinetics Plots - 1/T 0 0 0 0 0 ln(k) ­7.51 ­6.84 ­5.71...

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Unformatted text preview: 1/T 0 0 0 0 0 ln(k) ­7.51 ­6.84 ­5.71 ­4.97 ­4.68 ln(k) 0 -1 -2 -3 -4 -5 -6 -7 -8 0 0 0 0 0 1/T 0 0 0 0 f(x) = -9455.38x + 22.14 ln(k) Linear Regression for ln(k) Linear Regression for 0 0 Time (min.) 0 0.03 5.27 9.64 12.91 17.28 21.17 25.69 30.97 34.16 39.64 42.2 47.6 48.56 53.87 57.72 Concentration (M) 0.02 0.02 0.01 0.01 0.01 0.01 0.01 0.01 0 0 0 0 0 0 0 0 Zeroth Ord 0.02 0.02 0.02 0.01 0.01 0.01 0.01 0.01 0 0 0 0 10 20 30 [A]t Time (min) Zeroth Order 20 30 Time (min) 40 50 60 70 Time (min.) 0 0.03 5.27 9.64 12.91 17.28 21.17 25.69 30.97 34.16 39.64 42.2 47.6 48.56 53.87 57.72 Concentration (M) ­4.05 ­4.05 ­4.28 ­4.5 ­4.63 ­4.84 ­5.01 ­5.2 ­5.45 ­5.6 ­5.84 ­5.91 ­6.17 ­6.27 ­6.44 ­6.65 First Orde 0 -1 -2 -3 -4 -5 -6 -7 0 10 20 30 ln[A]t 4 Time (min) First Order 20 30 40 50 60 70 Time (min) Time (min.) 0 0.03 5.27 9.64 12.91 17.28 21.17 25.69 30.97 34.16 39.64 42.2 47.6 48.56 53.87 57.72 Concentration (M) 57.5 57.5 72.5 90.1 102 126.6 150 182 233 270 345 370 476 526 625 769 Second Ord 900 800 700 600 500 400 300 200 100 0 0 10 20 30 1/[A]t Time (min.) Second Order 20 30 40 50 60 70 Time (min.) Time (min 0 1.92 5.93 13.81 17.95 24.62 28.79 34.6 37.22 40.01 49.52 51.22 57.97 64.2 68.91 73.4 Reaction A Reactant Conc (M) 0.5 0.46 0.37 0.25 0.2 0.14 0.12 0.09 0.08 0.07 0.04 0.04 0.03 0.02 0.02 0.01 Reaction B Reactant Conc (M) 0.13 0.12 0.12 0.11 0.11 0.1 0.1 0.09 0.09 0.09 0.08 0.08 0.07 0.06 0.06 0.05 Reaction 0.6 0.5 0.4 0.3 0.2 0.1 0 0 10 20 [A] [B] Reaction 0.14 0.12 0.1 0.08 0.06 0.04 0.02 0 0 10 20 Reaction A ­ Zeroth Order 0 10 20 30 40 Time (min) 50 60 70 80 Reaction B ­ Zeroth Order 14 12 .1 08 06 04 02 0 0 10 20 30 40 50 60 70 80 Time (min) Time (min 0 1.92 5.93 13.81 17.95 24.62 28.79 34.6 37.22 40.01 49.52 51.22 57.97 64.2 68.91 73.4 Reaction A Reactant Conc (M) ­0.68 ­0.78 ­0.99 ­1.38 ­1.59 ­1.95 ­2.13 ­2.45 ­2.58 ­2.72 ­3.19 ­3.26 ­3.64 ­3.95 ­4.17 ­4.42 Reaction B Reactant Conc (M) ­2.07 ­2.08 ­2.1 ­2.2 ­2.22 ­2.28 ­2.31 ­2.37 ­2.42 ­2.43 ­2.55 ­2.57 ­2.69 ­2.76 ­2.84 ­2.91 Reac 0 -0.5 -1 -1.5 -2 -2.5 -3 -3.5 -4 -4.5 -5 0 10 ln [A] ln[B] 2 Reac 0 -0.5 -1 -1.5 -2 -2.5 -3 -3.5 0 10 2 Reaction A ­ 1st Order 0 -0.5 -1 -1.5 -2 -2.5 -3 -3.5 -4 -4.5 -5 0 10 20 30 40 50 60 70 80 Time (min) Reaction B ­ 1st Order 0 -0.5 -1 -1.5 -2 -2.5 -3 -3.5 0 10 20 30 40 50 60 70 80 Time (min) Time (min 0 1.92 5.93 13.81 17.95 24.62 28.79 34.6 37.22 40.01 49.52 51.22 57.97 64.2 68.91 73.4 Reaction A Reactant Conc (M) 1.98 2.18 2.7 3.98 4.89 7.01 8.42 11.6 13.12 15.1 24.2 26.1 38 51.8 64.5 83.3 Reaction B Reactant Conc (M) 7.94 8.03 8.17 9.03 9.23 9.79 10.1 10.7 11.2 11.4 12.8 13.1 14.7 15.8 17.2 18.3 Reaction 90 80 70 60 50 40 30 20 10 0 0 10 20 1/[A] 1/[B] Reaction 20 18 16 14 12 10 8 6 4 2 0 0 10 20 Reaction A ­ Second Order 0 0 0 0 0 0 0 0 0 0 0 10 20 30 40 Time (min) 50 60 70 80 Reaction B ­ Second Order 0 8 6 4 2 0 8 6 4 2 0 0 10 20 30 40 Time (min) 50 60 70 80 Zeroth Order 0.02 0.02 0.01 0.01 0 0 10 20 30 Time (min) 40 50 60 70 [A]t ln[A]t 1/[A]t First Order 0 -1 -2 -3 -4 -5 -6 -7 0 10 20 30 40 50 60 70 Time (min) Second Order 900 800 700 600 500 400 300 200 100 0 0 10 20 30 40 50 60 70 Time (min.) 200 100 0 0 10 20 30 40 50 60 70 Time (min.) Reaction B ­ Zeroth Order 0.14 0.12 0.1 0.08 [B] ln[B] 1/[B] 0.06 0.04 0.02 0 0 10 20 30 40 50 60 70 80 Time (min) Reaction B ­ 1st Order 0 -0.5 -1 -1.5 -2 -2.5 -3 -3.5 0 10 20 30 40 50 60 70 80 Time (min) Reaction B ­ Second Order 20 18 16 14 12 10 8 6 4 2 0 0 10 20 30 40 Time (min) 50 60 70 80 10 8 6 4 2 0 0 10 20 30 40 Time (min) 50 60 70 80 [B] Reaction A ­ Zeroth Order 0.6 0.5 0.4 0.3 0.2 0.1 0 0 10 20 30 40 50 60 70 80 Time (min) [A] ln [A] 1/[A] Reaction A ­ 1st Order 0 -1 -2 -3 -4 -5 0 10 20 30 40 Time (min) 50 60 70 80 Reaction A ­ Second Order 90 80 70 60 50 40 30 20 10 0 0 10 20 30 40 Time (min) 50 60 70 80 20 10 0 0 10 20 30 40 Time (min) 50 60 70 80 ...
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This note was uploaded on 08/10/2010 for the course CHE 2C CHE 2C taught by Professor Atsumi during the Summer '10 term at UC Davis.

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