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chem263_ps4 - discontinuous Show that 1 The change in...

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Physical Chemistry 263. Prof. Jose A. Gascon Textbook: Atkins 8th Edition. Problem Set 4: Phase transitions of pure substances. Due date October 19 2006 Problem 1 For a second-order transition, the first derivative of μ with respect to T at constant pressure is continuous, but its second derivative is
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Unformatted text preview: discontinuous. Show that: 1. The change in enthalphy at the transition is continuous. 2. The change in heat capacity at the transition is discontinuous. Problems from Atkins Chapter 3. Exercise 4.1(a), Exercise 4.2(a), Exercise 4.9(a) 1...
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