Exam Data Sheet - Revised 2010

Exam Data Sheet - Revised 2010 - E = E products E reactants...

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Examination Data Sheet N A = 6.022 × 10 23 mol - 1 R = 8.314J/(K·mol) c = 2.9979 × 10 8 m/s h = 6.626 × 10 - 34 J·s R = 0.08206 L·atm/(K·mol) pK w =14.00 K w = 1.00 × 10 - 14 K w = [H 3 O + ][HO ] initial a [HA] H × - = K p log p H = -log[ H + ] p X = -log[ X ] p H + p OH = p K w p K a + p K b = p K w a initial 400 [HA] K × p H = p K a ± 1 b a w K K K × = initial initial ) A (mol HA) (mol ] [H - + = a K initial initial ] [A [HA] ] [H - + = a K HA A K a mol mol p pH - + = log ] [ ] [ log HA A K a - + = p pH MM g Moles = = mass molar grams [B] ] ][HO [BH - + = b K [HA] ] ][A [H - + = a K a ac b b 2 4 2 - ± - = x % 100 % × = solution mass solute mass wt b a d c eq B A D C K ] [ ] [ ] [ ] [ = PV = n RT MRT = Π total a a moles moles X = solution mass solute mass = component w solvent of kg solute of moles = m solution of solute of L moles M = V m volume mass d = = initial final X X X - = o P X P solvent solute = o o P X P X P B B A A total + = nRT V = Π o P X P solvent solvent solution = [A t ] = [A o ] - kt C g = k g P g m K T f f = [A t ] = [A o ] e -kt 0 2 / 1 ] [ 1 X k t = 2 2 1 1 P C P C = k t 2 ln 2 / 1 = t 1/2 = [A o ] / 2k - = T R E A k a 1 * ln ln kt X X t = - 0 ] [ 1 ] [ 1 - - = 1 2 1 2 1 1 ln T T R E k k a kt X X t = ] [ ] [ 0 ln 0 ] [ ] [ X kt X t ln ln + - = RT E a Ae k / - = m K T b b = n m B A k ] [ ] [ = Rate components solv't soln H H H - = S T H G - = K RT G ln - = RT G eq e K / - = S total = ∆ S sys + ∆ S surrounding w q E + =
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Unformatted text preview: E = E products E reactants v q E = E system = KE system + PE system p q H = S = S products S reactants RT n V P gas = H = E + n gas RT V P E H + = G = G products G reactants V P w -= t = ) ion concentrat ( Rate l c observed D = ) ( ] [ 25 - = reactants f products f H H H - = reactants f products f G G G reactants) gas, (moles products) gas, (moles-= gas n -= reactants products S S S formed) bonds of BDE ( broken) bonds of BDE ( -= H...
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Exam Data Sheet - Revised 2010 - E = E products E reactants...

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