Chem%20127%20-%20Winter%202010%20Homework%201%20Solutions

Chem%20127%20-%20Winter%202010%20Homework%201%20Solutions -...

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Tc\'Ir+1 de, \ 'S WflIXff'c.cttd -t\rte C\.1hrQct1ve f Q'f't o-F t\n.€ Q_l_"________ Df' t wO COV11-Q\ Vl 2 . od M -t-VtQt H'2.. C)Q? C SVlQ\\t Cl, a VId \ O. 0 ,tsreC+-ive,\t\. Clf't: \VJ W )Q\ e!bl.l\ \ i 'on LLvK L \t\U,\) s Q\lV\t -re,WytJef" Q t:u..\le) b elt \f\D-t c"'-t\J\A \ CQ\ tq)W It b 'f \ U\N) ' DtCQ.LLst t \nt-\ CDVlCbJl-r-\fCltioVlS C l.'\t Y-. \-t 2 - CjQS, mer V1 =- n_ ='- (I a.+-Wl)(Lt.Q X \ 0-2- L) \ MOI-l 2 T - (f6:z..01o)(. \0-1. L.Qt\J\l\ :::. LUl2 10-3 \fV10\ VI I III x " to4 \ f)' \C.-') ( 300. K ) 1-e, \ fV\iVHLtt f e.-r WID '" 1.73)( I0 - 3 IOu 1 5-1 N=(f\) NA >( = ::.. t. '3 ><. Wlo'ecules s -\ 0 :) -t \ne- VlLL\M b e, o f u ll S \De di Vl I. cund of \M\tOc1JDV\d-v--\Q + 0 x \ 0 lD WlD \ ecuJ t s <5- 1) 4t1e. -Pi V)Q\ of ctY\<Swtr P l.s) Vle= WlDleS of et\AQV)'e ) Vlb ==- \I\I101e<s Vlt-t" Vlb::::' =- (IOS.S)( ! 03Pct)(2.l5 x lO-Y M"2I.) J lMol-'IC'%7.13 , 15+ Iq.2)\:J = +O+Q.\ V1e +Vlb W )Qs,:) :: V1e.rv1e. -t v1bH'o '" 0 . 3554 Y.. 3 (tlDO ",-3 \0 VIIlol lc:\i\lt.V)} lilt-Me + Vle+vlb = lO-!>W)ol- 37.0 CJ S) _ -1 VV101 Xe Me. + )(10 I'll b X'o =(37, 0 3 Mb = ( 1- Xb)tJ\e. + XbMb '" - 37,0 - S WlO\-1 I MOI- 1 Me = (31.°51'1101-') - (30,O(oq Me ( 5e,,123 5 (:,D,oLoq : ; lVIod - 0.2.'-16 '2 _ to\.ote. % :. 24.S 0/0 \fVl _ x. J ! \j \2...\ '" tJ"') 1 uco'Se., V \ cJ)1.. S - \ lbD. =: \ '/\ UJ \)\1)0/- 1 X 8.1Olo)(. \0-1. La:rW) tJlO)rl ( t.OOcx..tM l l.OOL )\ .-L2 3. w8 S ( 3 \Mol f I. \ l) 'P :: . !' R-L ::. x. \0-2. L \oar IMD 1-1 K.- ) (z.C\f2> W_ 1 -;. 711.3 bar l.DD L 'V 'I'D"tJ - \J - V) b I[) tl _ If) ' 2- ll- \}" fvP'tl =(3 'Mo\Xs.'3i4- x \ 0 - 2. 'ocu dW\3 UD\ -I )CI)(&cH2> j () - [C3IMo\')(O.02l.DS dW\3 MOt-I)] (LOOdM3Y-' -=- 7B. S \:>Q\ r'VP\J> 1-\I.e<•.\ f 1.W) I t) "'Ptot ::' _ 'So 10+eVl+'iaJ doVV\ \ V\Q+tCS. 2- tlr-e. re.yu. h"i \Ie.. , ctlT o f t-\ne, -fz.sa )(10-3 . - (t.D!15 x. 10' 'PQ X )eF (S.'3I't?;J;Dr' 1(-1)(300. K) J b) r ::: 3.25 lOt.4 PQ =- (O.lB 084-) (1.012.5 x ID 5 -pQ) -::. 2.l.D3 x lOll PQ f He::: Pfte e:, ItI2-T) =- (5.2.4 x lO-lD)(\.DIZS x fu)eJ - (q.OO'3Jt (et' Q.01 ( \1).0 X.lOSM :r MOr' k -'j .:: 'Po.. :p \.23) -p =: -po ::: ( \.0\25;( l o!:> 'PQ) =6."38 x l Diof Pu.- e- P \.2-1) -rlJ)e totQl V1LlWlber o.f MDtes o f t-t2- Qv1d "-.Jtt3 Ca\il 6e calcu..\Qted L LS\ V1lJ -t\;1e l v:-Po\ lM.cd-ioV\ \ VI +1ile f \t,lS VJ+r:+CL\ =: f\\I, ;: (1 12-T (9.Wlo"lO-'LL cclw!lMol-,\CIj(2.13.\SK) -(o.fJ3>l (0 1-) --5 M O\ VI "-lit, -::;. 1'1 V2-_ _ ( I a.+w\)(o.oqBl L.) 3 -ce:WlD"lD-l. LcthM lMol- ' K:1)(z..73'\Sk) : . 4 .40 x 10V11\l1i.3 -:::. VV)O\ XN H ; =. 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IOO'M)'%. . ::.: O.115W1 3 :::.. P't" = (4.2-5 I 1M \ OS Po.. '::;:. -S \MO\-I k:;')(325 \Q 1)5 L lOS 'PLl) T..f :: T :=. t 1f"r LV M + RP'!!ltt" tv T 32.Sk ( \ 1.47 ' ! \t" +- 1.00 to l 'PCL K =- I 'P,f- 1?,4i J MOl-I t"' + ( . I 'S'MOr- 1 K-')(1.SQX to,s'fb..) 7-.00"1.. l O"fh. \/+ = Vll2-T f,f 1..0:::: 'J.. (L1.1..-S WlO\'2 (e.31 YT'Mo\-\ k,-') ('=>09 2.€ ;O x (OS PQ 'K:) :::. 7.0S Y-.. \0 - 2. 1M3 l( -V..,J = -2·00 x. l06'P0-(7.05 - V.f -VL -;.-tJ.oox lO-'Z.W)3 - O.\ISW'\3) _ I f ( 0.\ OOW))'l.. -- 15 I. 4 2 VV\ : : . 1.24 IO&i 3 I f 2.\\ b} f 'i CLl\ Cu..\Q+t t\Jlt- f\ VlQ\ \/D \ lJJN\t tV\ -+-\At =: . \f t \ j (+':: I f) 2Tv-.f! '-J.lJi3 '/VI 01)(8::' IL\ 'k \ 0 -2- UoQf lMor'IC' X DY.'t!q '5 7. ,=,0 ' oQr q -rs+: 2S q L r'r-PVI-f =- V+om.\ - 'Jrf ::. lOO·OL - 25.9 L -:;;. 7 4.' L --Il.n ::::I YI-P \]l.fV'\ l ( __ ( 7.50 ' tn,) (7Lf.lL) CLf.103Mo[j(e.3ILt '" lO-2.. Lbctr lMor t leI) =: I.L{S '" l03 K. L1LL= VI Cv,'tV\ AT F rOM ::: (0. Lfq X [D"i]"" l03K-325K.) W = L03 X lOLl:r YQq+ a) L.Le k:-vjDW CD-=- w =(Lo.Lfq x l OYj)+ becQ.Ll'2.e fir,e. l IOLtj) = : 7.S'L X lOti"J p 2 ltD) £too 0 -Ir ::. .f 1roces'S i s 0.. diCl. W i c :;. 32') 1 : ( 'P' \ I -C. I. :p,wyev.1/V) i t) e:.;"""/cv,,,, K ( 0" 2.."'D xI 1'Q - 0/ 3 1.00 )<., llY K U)::..6Ll= ::: 8.42 )( lD3 :5 =- (\W\o\) =,DLl + -t- = LLl + :::. B.42- x. lO?:>:) = 1.41 )( lD4 j K- 'VV\ol-')(1.0DX lO,&K-3Z5K) Vl:=' 'Pi-\h :: L) 12-Ti.- (8.31'1 )(.ID-1. Lk:tt\ , "'\ '5 . 1foces5 eft!{) \oe.. c:ief:,a-, bed 'Step I : - 7 PI::' ID. 0 VL- 1 TI 2 : 'P,) 1\} \] l . ::. O.I1DI MO J step ; : ".Pi,} Vz,} T\ "]:V\ - 7' V i.) J" "Step l) Vi., T i. -...,. 'P,) \] i} T. U):::-D beCClLL'Se \J i'b LOlf1'5i L --+__ 1.0 '"Lr1 2 , t'" \Ji.)T, 1\, V'l-) T, r Z-.IC! 'Be.-fore CQI cu.ICthV)5 C M+ivlutd) Ti. \1\ VJ -Po" "&tq) 2 =: I w t \need I , -r;:o = 3 00. K. L 3 000 K w :: - lV'l -;. - \f'ItLT 1\fl -Pi t :::. - (D.40 J MO I ) lB.3 \L\: J \M01-\ = -2.30 x 10'1 3" (3CCO K).tV') 1 0.0 bil.( l .OO\aQ, :rV\ -ste:p 3) "PI \] :. "Pi. Vl. V PI Vi- = QD.Dlotlr)( lD.DL) I .DO b it\' - IDD. L (Osfa. ) I( w::. - fe){t fJ.\j =- - (\.00 -:::. ) )( bo.c x (IO.OL -}DO.I..- L = 9.00 'f... \0"3:r + W 'ist.2 + LU'St-.3 =- 0 + (-2:2.>O'l 104"",)} =: - I t' 41Ae CL\cJe flAe 1.4 lD 4 3 of: eCLCh fro.,\Jex-sW tVl +\itt . LOOf\:- -t--t\\J\A LOOU..-\ d ""bW\-tc\,] t00uJd p 2. 1.8) LL::. \f't t he \oec+- +Vtt tv, Wl ( 4 - T i ) =- -"Pex.+ ( Vof - Vt) -=ct=-D b-eCQLLSe.. t lIe. rfOce.ss \ CLd\ VlCv,W) v..J G lTf - Ti-} = - V')'R-"PeJ{-\VM T+ (If) (y,M +- Tp. - Ti. =: _ (C ' 1'00. k. u .) .,)<'1-_; =- T, (If', CV,'/V'I + 1<-1>ett '"Pi. - (T£ _ T j \ ?..p1\) 1- V) -r 11./ T IC'...r')( 1.00 klr') \'l.S b ar I.Do b Q\ __ - z.qO . ..,. J'K'lV\Cj-; CV/Wi - r R 'Pt'lC+ +- 'tx:\.() Lt:= -= n Cv,VV\AT -=- [1.1S VVtD\)(7.J(B.3JL1 z,qO '0 =- -l.L/Dx t01:r DH::: i lLl +- Vll.2-.6.T -=- -l.'10)l t03 J :;; - 4.00 X. 10 3 :5 ...
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This note was uploaded on 09/29/2010 for the course ECON 100A taught by Professor Smith during the Spring '08 term at Alabama.

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