Chem%20127%20-%20Winter%202010%20Homework%201%20Solutions

Chem%20127%20-%20Winter%202010%20Homework%201%20Solutions -...

Info icon This preview shows page 1. Sign up to view the full content.

View Full Document Right Arrow Icon
This is the end of the preview. Sign up to access the rest of the document.

Unformatted text preview: L1teNV\ t 2-l - v.) \V)1-a- 20)0 H OMtt00r'?- l S ot L l:riov)5 t h., : QLt..e-S1-\ \ . \ - \ .q t /,o\o\ems l .l} \ .6 1 \.1, loll; C\t).'2: 1'CO\o\ Q \. 2 . \ - 2. \ 22 . \ , 2.4) 2 .(p, 2 .7 1 2..11, 2. l{PJ 2 , 2. 2-B 1) l-ClNl-+\t1iciL ya.Cu-UvY\ <:. c o,k:.. <.. l-cVVl-tl1ick.. ( } - CW! - tin l ck- COffex' +lne- tVliCl:.Vltgs oP eo.cl-1 fJXl,ll l<5 I eWl, LC6 CllVI r QV) tltie.- .,. v o..C.UU\jY) nO ro.9Se.S t\J),oLlC\\n \. +, Q VB - t\,e. be.c£llLse i t's CDVlC,,\ete er t\!l SLLlo...-fo,\) to Jlowed \:>L\ (run ev..ttlt t V)t cO'{lci LtC to \ oP( E-V1erC\u..). whe.-("e e.QCVt of 4\A t, Wla..ter l oj ""5 'l \ VI dCl.i l L-\ II te, -\-\!1er\Mos, S CD.. rod t'D ItotUe..d 1oL\ COrl\A'SLllQtor 1 f o lIoLUeti DV)lj OVI -t\rle.\\r CO\Nlf0-s i i 0 v\:s . diQt-\ne, IfV1Ql b ecQu<Se V l rtu..aU .. +: co1r cone, L U'\ \Ie) etc.) ' %, I tt,. I V) of'lA€ -'f' L 00'f" d<5') H'l.- 0 I£:e\!lQ\JES W\O\\e, l \k-e C L fet:L\ idea--' I \y -t\Ao..VJ d oes tte. -rlllt:- FtioJ or Q tjQ'S l <S ck-f\ vled u s I V\ 1.7 ¥ ,\re.Qte, ttl-O of' +tne--yDttvdiaJ \ tif.t\ + \J)Q\fI 1t1e t\At. LDOLt\o. i f IT LDe\fG f ue. oV11L\ q tLS iVl +\;)eI f I+e\ nV)d NH-3 0€ e.. o.d!Vv\t'-tt-e.d to --\1A e.. '" I) Q \ feQC+t 0 V \ cuD LLl d o CCll.-r Q V\ d + 0 +qJ w O te. ! d \0 e., \M r 'rL-% . VI 'ftAe.. s tlw\ o-P- fCl'C'+\ QJ Q 1 .4) Tt-vvtfern._ttbre C1l..Vl\flOt ' ot Wte.ClsUS'e-d d:\ rec+lL\' 1 + \ S l\I\eQ?w-ed t'1Ile. efF'e{JtUJrt. OVJ CL flfO-plf s<1dn Q S t1J)t- VD lltwre Of' a. Ii ci l -H!l r rts . o f a CfQS, ftr1t-. e( fCtrl CLt J r e0\'?-f Qv) CL of D- 'N\t tttJ I 0 \ vo ltaqe. D.LX" --t-V\€.- j LlVl e. tiD\!) o f +tUO cii \NIl I Q\ Mt-taJ s. " - - - --------""- 1.5) Fi CLt LOV)cstavn- \/0\ LLVV)t-, f \ \VltOS- l'j l 0\t\n \ . C jO 1> =- eX ('J) T . Fi9t.J..re I.LQ "5\r}ows t\/l a l vV 1s a cOVlS+QV')T Q+ to\l)S+ClV1+ T . -p\J =rj... I IV\ d 8> Q \f e CD VI s to be. cle-,m \AA \ V\ed * fO\JV\ \ MeQSLLrtlfvrtv)Ts cunc1- +\irt LtV)i+s c\J}o'StLf) -Po, "v, \.} I QVl d T . I f V\ R ., -p'J =- V) \2..T. \. <showS + Q 1. (0) T F -+\t)e ? ste.W) WLL\f) oLttsl(J.,e D f title lif()U\d to V lS 'Dt wa.+e\), t int S ljstt-M eSCQ-pt- iTo VV) tVle roovW, -HIle , DOM i s ffir-nC\Vrlt1tt LUQt Is t"::, are, l ' l Q e-ed j . lS L UO-tt\r CAYl Q ' tlWl c.e.,. I .f -ti1e 0oLl\{) d QIll\ i 'S 1 0Q1l5 CQV) .i \fl '3i c k +\!1e. (i t , j Lt sf- d osed loeo:tJ-tse t QV)V)O +-) . C DV)tev)ts JQsc::, Q Q (.7) T lIlt M e l \f\ LD\N\p'fe<sstd q)H V)de\ 4:\ite\WlQl {COlt\ \l b'ftLlW) LO'lt1/) tlr1e of V \ Q \. 8) di.ff'e..(-eV)+ V \ C llf) \ faLUn d\ \ /\0.'5, \oLLt t\;te e.V)cia<s-td \VI Q 'S \i D\[\ Ltvv\ cl c-l\1\ LtS\t\;) exfl+t..t,e, . to I QdtQbQiic\ N) b1 \ w ill b L i if} L \oLLT V lot +0 CUf) lit 'MD )ecule" lflt tV)t'fg L\ Del O w. ' Iv) + l!)\S U lSt} f ue we,U di-pt'vl S\JV\aJ 1 ue.1Q+ivt to :fue t otQ\ l &) The.f'e -f6..-e, tine. Tc\'Ir+1 de, \ 'S WflIXff'c.cttd -t\rte C\.1hrQct1ve f Q'f't o-F t\n.€ Q_l_"________ Df' t wO COV11-Q\ Vl 2 . od M -t-VtQt H'2.. C)Q? C SVlQ\\t Cl, a VId \ O. 0 ,tsreC+-ive,\t\. Clf't: \VJ W )Q\ e!bl.l\ \ i 'on LLvK L \t\U,\) s Q\lV\t -re,WytJef" Q t:u..\le) b elt \f\D-t c"'-t\J\A \ CQ\ tq)W It b 'f \ U\N) ' DtCQ.LLst t \nt-\ CDVlCbJl-r-\fCltioVlS C l.'\t Y-. \-t 2 - CjQS, mer V1 =- n_ ='- (I a.+-Wl)(Lt.Q X \ 0-2- L) \ MOI-l 2 T - (f6:z..01o)(. \0-1. L.Qt\J\l\ :::. LUl2 10-3 \fV10\ VI I III x " to4 \ f)' \C.-') ( 300. K ) 1-e, \ fV\iVHLtt f e.-r WID '" 1.73)( I0 - 3 IOu 1 5-1 N=(f\) NA >( = ::.. t. '3 ><. Wlo'ecules s -\ 0 :) -t \ne- VlLL\M b e, o f u ll S \De di Vl I. cund of \M\tOc1JDV\d-v--\Q + 0 x \ 0 lD WlD \ ecuJ t s <5- 1) 4t1e. -Pi V)Q\ of ctY\<Swtr P l.s) Vle= WlDleS of et\AQV)'e ) Vlb ==- \I\I101e<s Vlt-t" Vlb::::' =- (IOS.S)( ! 03Pct)(2.l5 x lO-Y M"2I.) J lMol-'IC'%7.13 , 15+ Iq.2)\:J = +O+Q.\ V1e +Vlb W )Qs,:) :: V1e.rv1e. -t v1bH'o '" 0 . 3554 Y.. 3 (tlDO ",-3 \0 VIIlol lc:\i\lt.V)} lilt-Me + Vle+vlb = lO-!>W)ol- 37.0 CJ S) _ -1 VV101 Xe Me. + )(10 I'll b X'o =(37, 0 3 Mb = ( 1- Xb)tJ\e. + XbMb '" - 37,0 - S WlO\-1 I MOI- 1 Me = (31.°51'1101-') - (30,O(oq Me ( 5e,,123 5 (:,D,oLoq : ; lVIod - 0.2.'-16 '2 _ to\.ote. % :. 24.S 0/0 \fVl _ x. J ! \j \2...\ '" tJ"') 1 uco'Se., V \ cJ)1.. S - \ lbD. =: \ '/\ UJ \)\1)0/- 1 X 8.1Olo)(. \0-1. La:rW) tJlO)rl ( t.OOcx..tM l l.OOL )\ .-L2 3. w8 S ( 3 \Mol f I. \ l) 'P :: . !' R-L ::. x. \0-2. L \oar IMD 1-1 K.- ) (z.C\f2> W_ 1 -;. 711.3 bar l.DD L 'V 'I'D"tJ - \J - V) b I[) tl _ If) ' 2- ll- \}" fvP'tl =(3 'Mo\Xs.'3i4- x \ 0 - 2. 'ocu dW\3 UD\ -I )CI)(&cH2> j () - [C3IMo\')(O.02l.DS dW\3 MOt-I)] (LOOdM3Y-' -=- 7B. S \:>Q\ r'VP\J> 1-\I.e<•.\ f 1.W) I t) "'Ptot ::' _ 'So 10+eVl+'iaJ doVV\ \ V\Q+tCS. 2- tlr-e. re.yu. h"i \Ie.. , ctlT o f t-\ne, -fz.sa )(10-3 . - (t.D!15 x. 10' 'PQ X )eF (S.'3I't?;J;Dr' 1(-1)(300. K) J b) r ::: 3.25 lOt.4 PQ =- (O.lB 084-) (1.012.5 x ID 5 -pQ) -::. 2.l.D3 x lOll PQ f He::: Pfte e:, ItI2-T) =- (5.2.4 x lO-lD)(\.DIZS x fu)eJ - (q.OO'3Jt (et' Q.01 ( \1).0 X.lOSM :r MOr' k -'j .:: 'Po.. :p \.23) -p =: -po ::: ( \.0\25;( l o!:> 'PQ) =6."38 x l Diof Pu.- e- P \.2-1) -rlJ)e totQl V1LlWlber o.f MDtes o f t-t2- Qv1d "-.Jtt3 Ca\il 6e calcu..\Qted L LS\ V1lJ -t\;1e l v:-Po\ lM.cd-ioV\ \ VI +1ile f \t,lS VJ+r:+CL\ =: f\\I, ;: (1 12-T (9.Wlo"lO-'LL cclw!lMol-,\CIj(2.13.\SK) -(o.fJ3>l (0 1-) --5 M O\ VI "-lit, -::;. 1'1 V2-_ _ ( I a.+w\)(o.oqBl L.) 3 -ce:WlD"lD-l. LcthM lMol- ' K:1)(z..73'\Sk) : . 4 .40 x 10V11\l1i.3 -:::. VV)O\ XN H ; =. [ C);l Q Q +\Ae.. l,)..:)orkl'S doV\e- \V) csur,oU¥)diVlC\'S. ttecct- +'louJCS Q C)[OSS +V1.e.. boL..-l.Vl dCLV-L\ be.+Wttv] "DLL\f'f"own.dl VZCl.S a VId e S L\ ben::o:l5t.- or +It\t.. teUV\ner-o..t-ure. ..J cUfF'ertv\ce -t1n. t-\M . T '2-.2-) :z:v, t ile LllI'(:::JU 0 i V'l C\. acl \oj') ccl-i c- t.)(VCLIfl ':> t o I I) , 1 -.\) :-U0rk.. i 6 dOV1t O\[) Df+i(" Vl-h>taJ Lf.L.f 0 '" \ 0 -'3, VV'D \ l.D .to '3> X- I 0 -:3 \JV\f)\ ::: O. LoY. 1.1 z, J Q. 2 -.3) II) i 0e(l V'll:\ b.lL, t:tInd o f % '{ tL.wtp era..-twn f:, Ij CiJI!)ttrl..g , "50 Me. DP tine. L.DO \ " do 11)1:. \ VI -t-Vlf.. iso+lite'i\Ila.1 &pQlIlsiDVI CCtYI c .DWlt cd- tine ex.Veln'2e.. o f --itt e, \n. fV\trl- V\Q<0 +-1 0 LUW n.cr O S S + t, t:. boLlVl clCL\\l\ be..-hU':fn -Ht:e <;.1..\-ste..'(V) l\.1J/?- SUJ'{i)llJn& IJI,3S (.0a.;I-q- d.. 0 li)to Mne. \VI C-IIeQS \ tIllt'o' COViVer-SIOV\ o f SQ5 + 0 l i tid . \ lrti S TlfCJCf.SS LS t:S-oevrt--iQ\ i t\JcrS\ '0\ t+lne IJI)J-e.. 0 VI of 0oJ-et- i." If)tQ Ij tqj-W -tv +\Ae Iftl.:tt 0 f ' al\ +tr-te- cioV1E. l..i.'\VJ en-r r ci.e-1°'S\1-l 0 V). I & r v1 Q CSLi\ \fO ltV"') cl\ V1C\S :XVCl \f)'5l0\l)" : \ne Q\ w"t +-\.t oV\t (i\Aot\r\e,\. -r-Vl CbR 't \ f{e \Je \\,S\ '0 te exvClVl S \ OVl) ·t\ire:J ().I\" e 1I)OT i VI e'tui hb'f \ L l.'M 1O i +\.r\ 0 VI t , L Q\ t VI -t:Cf\tJ::V\ \ 'of \LLVV\ Qv\d Q 2-.5) Heqt \5 \/leVerberltLtse Q .:stQ+e -Pllflctiov) t\JtV'\ i f +iIle lntrLiLV) I I f"oce..:=,s \rtl5 QWfllC{)llf voJt.t.e at ti b f'\ VlDt(t Q l .la) ttefLt (en) t\A e 'tS -p(Y:Oit-\\Jt \ntCL+ fJ..L\OSS - 'StU \)0 llVl ci\ V1ij \y:) lUI) d cos- j \\lito 9 1/)c T lttt lW] t S Ult3Clh\JtttccLLtc:st lUO,\::- OVl t\t\:e. Vtrp0tr,' "b'l V I] ' SLtf\fDWJ)d\V)l\s. 4 LL 15 y Obltl\Jt i Q 2 ,7) WJld C£JVVlf:, l llbLL\d i S 1'lIlt os i'5 OVllj tVltw), \ caJ rC'QChDV) we CO WYP ° I f' I I 1'(,0 ces'S, ' 5ULIi) Q S ct. lVi t \nl5 CQse) OCCLLf-S t v '2,'1 h 0 i f) D-f- fut 'ZllQ'5Te.\JV\, \ \n d:SG . .LV) d o \ ClVl d ccb w \" be.d bl\, 0 V')O Q 1.S) Hea+ l ? V\ot- [l [t- c.o Vl ci-e-V) ' C t:S +0 Th-t- \llb Lt\ d ' 50, '?LLD<s-[Qv)Le +\;lQ+ CQV) b e <&tor-td. ' ,'S '\ V) CD\f)tQGt, LU it\A L \0LlrV'\ J \ VI -Hn e fVlQl5e' clnQV)t\-e Q 2-.q) t+ea.+ ,Dvld -t\nt ++0+ ( '5 \ie. \fQse.d S QW\e D CCU-("S. d oes lIlot \ le\ffi.£f. s \ tLtQt\ O\{) b-eCDL.L - hrLlVlS\eV'lts +\i1Qt f Oif) 1 L\ l V\ +tne + rtl\() S l t i 0 V ) \oe wee Vi ui t\ 6 \f \ \f\I\ * fes. fo'f'C:) Q s+eW\ e£O ll\ 1\ '0\\ t LLW\ UtV1V\O+ 1JIQ\Jt a'SSOclQted \;)eQ+ + Q+ ao (() \ " , u.))\1 k- . QZ-.IO) A -to IMQS'S i s Oil) c..D\N)'P \e.te. t o v) \.l i f 'Sl OVI c f Q 5 r i '=>toVl , t o II Cf)LUcf t - l Vl<SLt \ QW I -t-\t1 e ().)Q H L0er-e V)e.ru-l L\ Q d \Q bcL+1c. -{-tIre d id n ot f a II 0..-:, \ft:\:p i d \ l j w/A eV) i V) CD V)1tl.f;t- IV (f u t \;l e cool b \ 'V\..l.\lIlOt..lV)d.i If)CJS t'l'S WOLL! d \nruJt beo1 -tine Lf iVL-t LlXUl D LUt:X'G dt·aJ-{ntJrMaJ. Q 2.\7-) Heat f'IO(J)tVlC\ t:iCf"OSS t\r1e bOLJ..Vlm\rL\ be-twteV} +V1-t 1iV) d 'SLlf"I{D LU!)d t VJ({S w it{ t-eQd 'to Q, +eVVi t e-\lQ+u-\re c \ \/llJ..t\ne. S LL(' ' folU\ d\' V)d S 1;)1 \.leVI T:=o . LVI =Fit! i s ' 5 i + t-LtL+i o v) I J tLej Q z..It) H-ea.t- C!lIl)'t- IDe ,,&tor-ed t ff,QlLst i t u ists 0\1) I a s Q t Y)-t LDfreL-+: "6ecnu.se. tv1e lAoLl'Se wCLS \OJ A CO -_ - -S.ZJ-l x -=- - W)c..l'.6T = --(t.DOx \(fo..)(Lf.\QJ3"'K:-'\(./.V;K) 101>3"" J.J P 2.1) 'PtJ-o.- no.\ -::V,::, \. Vll2-T ::: IOJ'PQ + ::.. l ff""l- ID:)'D ret .;.JS7SIktJ)(q·'O\M"S-1..2;:.zeoxlo 6p(\ T ( 0. IOO'M)'%. . ::.: O.115W1 3 :::.. P't" = (4.2-5 I 1M \ OS Po.. '::;:. -S \MO\-I k:;')(325 \Q 1)5 L lOS 'PLl) T..f :: T :=. t 1f"r LV M + RP'!!ltt" tv T 32.Sk ( \ 1.47 ' ! \t" +- 1.00 to l 'PCL K =- I 'P,f- 1?,4i J MOl-I t"' + ( . I 'S'MOr- 1 K-')(1.SQX to,s'fb..) 7-.00"1.. l O"fh. \/+ = Vll2-T f,f 1..0:::: 'J.. (L1.1..-S WlO\'2 (e.31 YT'Mo\-\ k,-') ('=>09 2.€ ;O x (OS PQ 'K:) :::. 7.0S Y-.. \0 - 2. 1M3 l( -V..,J = -2·00 x. l06'P0-(7.05 - V.f -VL -;.-tJ.oox lO-'Z.W)3 - O.\ISW'\3) _ I f ( 0.\ OOW))'l.. -- 15 I. 4 2 VV\ : : . 1.24 IO&i 3 I f 2.\\ b} f 'i CLl\ Cu..\Q+t t\Jlt- f\ VlQ\ \/D \ lJJN\t tV\ -+-\At =: . \f t \ j (+':: I f) 2Tv-.f! '-J.lJi3 '/VI 01)(8::' IL\ 'k \ 0 -2- UoQf lMor'IC' X DY.'t!q '5 7. ,=,0 ' oQr q -rs+: 2S q L r'r-PVI-f =- V+om.\ - 'Jrf ::. lOO·OL - 25.9 L -:;;. 7 4.' L --Il.n ::::I YI-P \]l.fV'\ l ( __ ( 7.50 ' tn,) (7Lf.lL) CLf.103Mo[j(e.3ILt '" lO-2.. Lbctr lMor t leI) =: I.L{S '" l03 K. L1LL= VI Cv,'tV\ AT F rOM ::: (0. Lfq X [D"i]"" l03K-325K.) W = L03 X lOLl:r YQq+ a) L.Le k:-vjDW CD-=- w =(Lo.Lfq x l OYj)+ becQ.Ll'2.e fir,e. l IOLtj) = : 7.S'L X lOti"J p 2 ltD) £too 0 -Ir ::. .f 1roces'S i s 0.. diCl. W i c :;. 32') 1 : ( 'P' \ I -C. I. :p,wyev.1/V) i t) e:.;"""/cv,,,, K ( 0" 2.."'D xI 1'Q - 0/ 3 1.00 )<., llY K U)::..6Ll= ::: 8.42 )( lD3 :5 =- (\W\o\) =,DLl + -t- = LLl + :::. B.42- x. lO?:>:) = 1.41 )( lD4 j K- 'VV\ol-')(1.0DX lO,&K-3Z5K) Vl:=' 'Pi-\h :: L) 12-Ti.- (8.31'1 )(.ID-1. Lk:tt\ , "'\ '5 . 1foces5 eft!{) \oe.. c:ief:,a-, bed 'Step I : - 7 PI::' ID. 0 VL- 1 TI 2 : 'P,) 1\} \] l . ::. O.I1DI MO J step ; : ".Pi,} Vz,} T\ "]:V\ - 7' V i.) J" "Step l) Vi., T i. -...,. 'P,) \] i} T. U):::-D beCClLL'Se \J i'b LOlf1'5i L --+__ 1.0 '"Lr1 2 , t'" \Ji.)T, 1\, V'l-) T, r Z-.IC! 'Be.-fore CQI cu.ICthV)5 C M+ivlutd) Ti. \1\ VJ -Po" "&tq) 2 =: I w t \need I , -r;:o = 3 00. K. L 3 000 K w :: - lV'l -;. - \f'ItLT 1\fl -Pi t :::. - (D.40 J MO I ) lB.3 \L\: J \M01-\ = -2.30 x 10'1 3" (3CCO K).tV') 1 0.0 bil.( l .OO\aQ, :rV\ -ste:p 3) "PI \] :. "Pi. Vl. V PI Vi- = QD.Dlotlr)( lD.DL) I .DO b it\' - IDD. L (Osfa. ) I( w::. - fe){t fJ.\j =- - (\.00 -:::. ) )( bo.c x (IO.OL -}DO.I..- L = 9.00 'f... \0"3:r + W 'ist.2 + LU'St-.3 =- 0 + (-2:2.>O'l 104"",)} =: - I t' 41Ae CL\cJe flAe 1.4 lD 4 3 of: eCLCh fro.,\Jex-sW tVl +\itt . LOOf\:- -t--t\\J\A LOOU..-\ d ""bW\-tc\,] t00uJd p 2. 1.8) LL::. \f't t he \oec+- +Vtt tv, Wl ( 4 - T i ) =- -"Pex.+ ( Vof - Vt) -=ct=-D b-eCQLLSe.. t lIe. rfOce.ss \ CLd\ VlCv,W) v..J G lTf - Ti-} = - V')'R-"PeJ{-\VM T+ (If) (y,M +- Tp. - Ti. =: _ (C ' 1'00. k. u .) .,)<'1-_; =- T, (If', CV,'/V'I + 1<-1>ett '"Pi. - (T£ _ T j \ ?..p1\) 1- V) -r 11./ T IC'...r')( 1.00 klr') \'l.S b ar I.Do b Q\ __ - z.qO . ..,. J'K'lV\Cj-; CV/Wi - r R 'Pt'lC+ +- 'tx:\.() Lt:= -= n Cv,VV\AT -=- [1.1S VVtD\)(7.J(B.3JL1 z,qO '0 =- -l.L/Dx t01:r DH::: i lLl +- Vll.2-.6.T -=- -l.'10)l t03 J :;; - 4.00 X. 10 3 :5 ...
View Full Document

{[ snackBarMessage ]}

What students are saying

  • Left Quote Icon

    As a current student on this bumpy collegiate pathway, I stumbled upon Course Hero, where I can find study resources for nearly all my courses, get online help from tutors 24/7, and even share my old projects, papers, and lecture notes with other students.

    Student Picture

    Kiran Temple University Fox School of Business ‘17, Course Hero Intern

  • Left Quote Icon

    I cannot even describe how much Course Hero helped me this summer. It’s truly become something I can always rely on and help me. In the end, I was not only able to survive summer classes, but I was able to thrive thanks to Course Hero.

    Student Picture

    Dana University of Pennsylvania ‘17, Course Hero Intern

  • Left Quote Icon

    The ability to access any university’s resources through Course Hero proved invaluable in my case. I was behind on Tulane coursework and actually used UCLA’s materials to help me move forward and get everything together on time.

    Student Picture

    Jill Tulane University ‘16, Course Hero Intern