HW5_Solutions

HW5_Solutions - Chem ll“? * Homwork 561' 5 (0.21, (9,7,2,...

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Unformatted text preview: Chem ll“? * Homwork 561' 5 (0.21, (9,7,2, (919,538, 35,89,811, m)qu % M005] -\- 427043) g.|5,9.l(a,8.16,8."l0 In'rl'i [41’— OF «.22le H00 0 O Molcs@e¢bml- “00’ g g M l 62$???” Hoe-g % 3% L .00+J,:§ Vberial Wane L! adrezbmlibrium<m Gig P FL “" X1? 14.00 +L£ 1’ Gong— “4:0 H} z i COO-g 17 14.00 Hag P° Li” % ‘7 ° 4.00— g 4.00 +1.? q.oo+i;;§ ' P 11 b) E #8 Pf __ 7, 400+! 1’ Lem — 4.00 fig 4. 1? 3444.00 KAT)?“ 31f; 3%” (—11%; c) To solve For gm mead Masai-trait:ch 133;: AH}? 1563? AGE: (MO;%U"AGE(NOCIé-’— 8710 “%o\ '“ (00-! Wmol = 2'5" '03 X10! AHL=AH3M®~A4+3moc159=4159mr 6‘7 Wm = 5% “03 7mm flnILP(m.15I§='—5‘—§-% =7 fln KPCE)= ,Qn K? (Mg-‘59 “$3;- J11; — 342-575: n-AG:%.(248-15Y>-AH?L( l _ _L_d "LnfimgK £1 T41 248.\6K Ml c) confinwad ‘ . KL K>_._(Zl.6x|03'5mo|"2 gBQLoxlosjmol‘g l __ I 1‘” V 375 ' (9.3HIK'mol“)(1%.\5© 6M3 K"mo\" 375K 2485K : “5.390”? 1419(375I4): LL51“- ’0'5 KPH)? fiat—$.73?" 1r gLL LLOO (sec pafl' b) g: 85 K? 3 : [Wimw m" Degree GP diefiodafionlgzogso d) Solu'm +lAe, KP ex x1530“ derived m cur-1' Q wlfhoufl' awogmojfions 5333165 §=o.llq 1) EC‘CL‘HUOL CH'OV = D-llq “(f-‘20 : _l'65% 0-” fiesume, checL\ 5&5 behavior. 56mins: V1123- Xe Qn X1, “7-” 3.10 mole}; + ZHS MO‘CS 1' 13"] melts 7- molds AGIMH =Uot‘5q (fiestas! 3K" * soKé-LD 2L0. 3-5.5 2. 1. .' “3 m) L, max?) )Lmflnammm (amfiwfifi : 2.0mm“ 360.35% +(-D.3(08)+C'0-5‘3)] :- Auo x [0315 Aswxivg: 'V‘P-Z XL in X}, = — (0.301 molc‘aXB-BH 3K"mol")[‘;%’,rfln%%.3— +§§0~nfi *fi'finfiiq] : —5 7.3 3rd [-0.556] draws) + (“MW 5 5% 3K" Etbuafiom (9105‘ -. - Ah‘" __i__fl , 1 ) ,Qn \Lp .Qn Kp(zq8-ISK) B- E qul‘BK A”? An: (cozpwHfimugv amines) ’AHflHzQD 1 -593.5“3/m0l + O + “0-5 V‘s/MOI + 285'?) D/mol =- 18 %‘ :2 1.90 x l03%01 ‘__L__.._. ‘ _ [Z 2 '1? 26:3.1514 AH}; '” [49(73st .1 x _. 8.7.4"! 'SK"moI" 2 129923— 120X '03 %o‘ ' n '03 = 5-35”D*10'3K' - 2.47. x ID'3 K" = 6m x 10-“ K" TL = \.07 >< 10% K K? Increases len MEQiUR (ballast; W flap/HO“ 1‘5 endonAtfmiQ so as 4’00, ,Lagfi. l - "Kw—“Q K2(Tf’7°°) 00 298.1514 AH“; “ Kpoamsg gm (T 5200) _ AH; :2.80xm3'siw\ : H3 K17 ZQQ-ISK ' UZ‘IBISK (BSILiB/"me-Lqmag @(T—voo) = Kpmalsbc'“ 2(332 x10’~‘)( 3.10) = LOB x to”l . - 1> H3 “9 KP’ “A” where “P”: |bcur 6%"? @ ; Pmaz PHL \bQF-‘J 1.].[05‘PfiL‘l' 1P”; z PH). 17.4,; 0.3m: bar PM; owl—t box (9.38 a) oom’rimufid @ ECOK [ W: [.095Ph4'17uz: P”;- DHBD bar m3 = 0.510 bar : 0520 a KV(Bw'© (eyeojé’z “5a) b) assume AH; 'vs mdeycndenJr o? +cm?crcérufc . LAW-K ., rAH°( l ___J_. am'b'bs ' Q“ KPCIDOJQ 12,1 300.14 700.14 , (801KB 1.5a AH; =— Law name" 716' jawbrjlflmor‘zfln 335 :.—L“"', 9' ---—-'—-‘—"_—"—-—O w __I_,_ I " 1.7.5K\0'5K"_|.‘13x|0”3K' ml; 700. AGH-room = "El—11v) KP (700KB = "75% WW Aamm v9 = —lzr12m<p(%0O-l<) = “2% Wm A52. (700. K) = W .1 A”? "J’wl +73% “*0! 700-14 700.; :’%'%%wl-K A$°(800.|4 —_ AHL- 16300.11) _ «1.7"? +29%. IL 3 W“ “W: ‘99.L|%DI.K a) 136326131514) = —IzT.€n Ii? (7518.152) _—, _ AH” I ___L__. in IL? (2%.ISK) fin Kpbomc) Pf mm my) :. Q 355 +(LI.I7KID"3ZWI>( ‘ i I V]( ) 8.5M'SK4mor‘) ZqBJSIL 760.]: ill-0 A631 2%. IS K) = 19.3w SK’WI'DCMBJSIQULOB 32-75 X H)4 DZ“), : 27' 5 LL:S/lnlvm‘ a) _:_ ASfiinIn x Asfnasion mug—6m. 8J4 :- d’T Fueion AVfif’mn Mug f M“ 0 AH... ‘0'" gwswn 9w asmww T 9.2. (99109,; a CW 71 T/ zfilt‘lauzm‘ ZZ j/K'mt (751%? *1 W0 KM" = al.145x10717mK" = "[45 bar K" . 13.02xlo‘3 _ze.ozx;o% Hombrnkyrg) (410130.? (um: 137m! = “’60 The, Yfe‘ae'ure \Mufi-f b6 increased b57213 bar +0 lower Hat: mtlerg TOM? b3 50°C. - F _ ‘ — ‘05 P’T'(% Mm; =z.leo7PaL=Z.leO‘bar (16x \0'1m)C7.5x I 0%) 0)AT= i.) .___ H4 1 o (d? med-mm Ham (“W WP l-5K --— Lsc so, Tm ‘-’— " [5°C A) No. Tm umder +w'sYrcssurc is area/fir ‘anm +14: JramyeraJrLLre 010 +Ine, ica. 0L) Diamovxd 15 denser H10,“ @rfifififi Web, "For a given WPCVGJ'LUC, +Ine, yhaee/ wiHn ‘an Mighty demaer will b6 {band 0d" higher Fffi$fiuge (Lt Ohfifditl‘é Princifle) b) szyhi-rfi is dam ~Hnom “(ht/kid carbon bwuLfiC We elope 0F -H/\t graphihiv lirbw‘d COCX'ISW Hum: is ‘ HWC. H eiwflar cur aux/\ve +0 09 can 6L| be, used (comich «Sarcasm i CVCCLSC (1+ Oflium JremApcrai’m “has? 63035 'H/NOUESV) van We {trath and Ii (£ch wages). c) The yhaea d1 has 2 Jrrifle Toix/fifi because, +u>o Sohd Wages chair. MulJripkc +rq>lc TO‘NHS are, owl Yogfiiwe LOVED MOW; ~H/1rm owe, eolid yhast (Lgc, in rare CQEED, more, ‘anvfl OWL II‘CDLU'd Thea; axis-h a, No. The; va or measure 010 fine 1i and decreaecs - )wi-Hn MCI’EQCQI‘E) +cmPCFQi'LLU‘C C?ndic&+fid b5 —Hne, «1+in 6| (9? fine licbw‘d" vapor made me, line). The diagram indicafree a, eohdvuapor orifical pom-f, which few—F wesiblc. fie Jane IiCDLUd is Cooled, i+ vayomgcsr which [5 phufieimllfl unreasonabla. b)No. 9+ ymsewrce {fies 44mm Hm: er‘ple, POM/fl; Hm, liqyjd eclidixciee at; We +€Wcrodmm Mamas) which is no’rafoeeibla. HT awmfw/fi fimpemjwzs, am warmer: in flecoswre ailments fine eoll‘d +0 eqblime, which is unreasonable. above Mae, +u‘iPle Point .Hne vagar‘eolidifleg gig.me cheewre coffin MOW aeun +6M17cfa1—m coma} i6 no’r Toeeiblc. The aha -ifldxca:l'€5&eo|f w licbuidariHcal yam/9r, LO idA camo+ fixist PM? 09145!” K,l050Pa Single‘bha‘se: 3‘15 b) l‘15.l-IIIA,0077 Ra. +ri It mt a hoses: g1; ‘igffld,%ofiid 0157.?! K,¢332531pa, d 6W} C. $5: d/Mw ,IEOXIOSRLCUJ 6m Ia 19mg; -. Saga-Wad Fluid 62 tqokmowm Cainfl‘c ?Vnse,:solid WWW ODOHI . 1/T 045') ‘ ‘ V For a \icouid'flas chLUUbV‘iLLM 0? a emglc spams: K9575;- abuafrion (2.023 = din JAE. T 2T1 AH ‘9 I dfln m C L) dT 4dr ET __F¥_Z}__ ’ PIT?” ‘91 Hm fiflfits) = KTZHL) 0LT— EE +—nm]z : " (70.0 3m" K"'- leesjmor‘ ")(5- 5005) = imp Tmol“ ...
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HW5_Solutions - Chem ll“? * Homwork 561' 5 (0.21, (9,7,2,...

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