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HW7_Solutions

# HW7_Solutions - Chcm IL‘I wm er ZOIO — Tember Homework...

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Unformatted text preview: Chcm IL‘I ' wm+er ZOIO —- Tember Homework 1W: I03, 109,015, (0.4 , IO.\Z, l0.l(o,[0.ZLo, 11.0115, 1H, NH, ILI‘S __ __—..——_ _—-.—— u-w--—----—.....-- _'_._._...._'-—F' 0,) ‘QaBr 577 N03” 4' Bf' 5'0“- ‘0-50 = I "* 1%:wa Hi?) Jim: + mi?) 3;: i2; (0.0055 ma 1“ + 0.0055—“ﬂ—sq1)=0_0&35m‘_ "S "5 “35 WNW a“ X3:'l"75'%+i'\ Lilli—kg" 0n ‘1; = 4.173] “1‘ [0.0055 -- 000qu X: : 0.615 ‘0) \$70!; tr, 6r” + 201* 1‘ i710. oozzsngsL wk 2‘ + 0.0025L‘ﬁg x 17*) = 0.000752% 1095:: *I.|73)u1\ (0.00075 = -0.l85 \$30.05 0) CQHPOL, 5:, CM1 + H190? I=J-.001'M°‘ 1 ”—DL 1._ 2(0 51? z + 0.0015 .33} x z) _ 0.0000ﬁ-‘g‘3L by 11:: 'I.l75luz‘.[0.00(90 ; 00.50%} \$5?- 0.70 I =%(u+z:— HLEE') (:chon 4;; Ca” + mo; :0: @(mzw Lxl‘)=.0.15022L MW ‘3; New HM” 3 349390—002“ x11):0.0500-ML' _,_ “5 Mobﬁoq -—"—7 M03” + \$04 1‘ °‘°§°°(1x2"+1v2‘)= 0.200 09‘ 10H comfimutd mot-3, i=7 m+5 + Bar 1.; 0.0550 (l*31+ .5! x‘L) 20500391.. "5 - For Wamxswwk acid HHL—a H+ + H” __;___a*a5' 2%?“ "+ m."’ v- X‘f— X“ :(mol X1- gr ©0625’(M "1° 0- OEZE'(m-) [10* ‘0'1 :7— W) M°_—,l blﬂ' m g 5... Cure an" unknown 30 For a 00515—— 13; Q €1re+ moxinfwaﬁoﬂ 2(90 [Dd-m 131: lbsolucForm M:- . K __ “‘5 I: j'ﬂZv—(V-fi: + V..£.3-> :' LNi- Ix [14?) g‘L)Z_WT\i—(z) :- m 0n 731 7— 4.175 I lleODZlo : 4316‘]?— le 0.82% New mil—l— we have an awvosdmaére ‘61; vcﬂuﬂ, use, 1+ +0 vecaicmloére mm, mm mnowwr 7h 1.1mm; :. (333); 3/4: 2 (\$1 (0.827(0); DOBW—Tn: 0.0825" no m: 501(1) X ‘04. BEL I= m=5.01(9110’f§9l. Qm if: : «1.17am [liféaozu x10"; : ~02qu ‘6? = 0 615+} 7’0“ ”3'79 M)— 0.0326- W\-' 5.0100 >4 \0'1 ”‘0‘ "5 10.5 cmh‘mued I =— m =-— 5.0090 x l0""'———WI "3 2n 1%.: 4.173)” M 3.0u0x10"’~ if; :2 DBMS [10x [0‘2 : 33;)” (wall—ls); 0.0835 fire; M 5 5-0393" '0": "'0' «7 was value is close tnou 1n +0 “/16 k5 Previous calcmcm‘on (a. moxlO'Lﬂ‘EL) +0 «5+0? we. iteraﬁms hen: k3 0.050(5) _“"_°L m “00% = 37% 59) WWII? tree 04‘ dissociaﬁovx (15m we liwu'Hl/l (a U0, In lﬁd’ilﬁg 6 increase m iOWiC 3‘“an Tradiacd U3 acid dissociaﬁon _, .— \Mol I \M 0.200 is Jin‘gt == «75] I x l Home : -o.51% ‘5: = DPEﬂIB Dow calaQQ—jrc :an, comm-rmﬁon DP ‘HAC 10% Weed b5 acid diesouaiion m solwﬁon mm Xi=0501l8 m 7— LLOHO'L-Léwm") 3": 00823—135 M; 5.57 x 1011M ”‘3 Degree, 0? oliesodaﬁom = 2335 x :000/0 = ”7% 10.5 cowﬁnuucd c) From Table, 10.3 -. YtoolmKCJ) : Drug l-w‘lJO—Z :'- 'M—l 0-7 L (W10) ( if) :7 M: 5' 57 X ‘O'-Z- MO‘ 0.0815—W k3 ‘ - - _ 0.0557 Degree 0‘? dlssounhom — ODBIBK [00% :LHO/O UJOWLMS Wmmgh 1+er0L+iUC calmloﬂrioms «For \o % c, (as M6 dome «Cor ﬂ.) fwues +0 \06 ummé‘CCSSG-Yb benause, culwlq+ed valums OF M do wo+ d/ﬁmge mud/1 Pow smegma iJrCWaﬁonS. CL) Bad; 9:1 Ea+z+ ZCJ" For 0.5mm BQCIz, Kt: D-LHq Ma '-'- H.00x10"4 -:. WI 7' 2 — = oomoomi. (may {i ’7 m ”is mom—"\$- V fee oPdiesocia 'om -= WHOOM at) +1 WHOM/o 114.0% D b) KDH-é'v 14” + OH' k5 For 0.3mm my}, 5;: 07‘12 - 7—4 2. [+00 X ‘0 ‘4 -;_ E36! (07142) .3) m:8_|UBx lo-s “Rig 0.100 “Mm; Weaver? 0? die-mm = a W x '0’? "‘0‘ 0'00 m_ XIDO%=-'Ebl7% C) Rctmob—h‘r Hg + N0; '3 For 05me 95mg, X; 01900: HDD M0 = ﬁsﬂouomj’ 9,7 m: ‘MZ >< (04329;. 0.100 — —“"—o- [“5 p65 \le-i—lo‘n 7" W 2, K [0013/0 :' (iqzoﬂp '09 cow’nnugd In ~H/le, absence 0P 0+hor :«lCC/ﬁoltgres 33;", HDOMO’”: (2%: :1(%7:m_:?mg'5bl3xm-4 ¥or Mf- @ 7934‘ AGZduodion: 2" |_LpOleO"“C 1((9012x10ﬂmol'9 (__1____|) BTHBﬁS—l no"? 3* M’Br 5 :7}:— (Logsmlo's 3w!"- m) r " j: (b.2567 an [0" L'Smol’VFM) For CD.” 00an F: 100 PM A6;ud'ion 7‘ '65):— (085771: [0414;5- mol'LPyb :— -Z.7"' KID" Iii-MOI," counter dﬂdﬂ‘gﬂ‘J— ~ch re/ ”oh“ / \\ d(—— a—CbK re, I‘1‘) 1,.(bKe—LFMP +%K§F a l ' ‘1 MP 1 . =0 , ’ "1’3 7 "“ \ 00’ , , WWW —+q§l¢ FMPW P r"? "z 9, I/mol- , ’ (1MP 3-K zmuol er [‘5 ffWMI :quuoqlfw 455cm [031 —'—— —- “moi/“g (way—mi 3) ,aﬂxlo‘tl 735(zm3+\xz)— IMHO" —I 44““ F FMP': (9'4 X lO—lom : owl/“Am [0.20 v: V++V, m;=m‘jrm: 03001005); =9 v+=\ xix—7, v=5 m: = (0.0500)‘ (“0.050031 =. 6.00 x 10'”.mn|i has ”‘1 = 0.07% LO' “5 b) moH => v+:\ v-=l 4% m: = (0-CBUOU‘L0.OSOO)'= 2.5 x [0'5 ml; m1: 0.053001% ‘63 @0360, =7 hf? v-=| \lr-L m; “-1 (0-0500)‘(0-0500)' =25 “0'3 MO“- k81— M: = 0.0500 ml ":3 dz) Filo/'5'? V+:l V..=5 v;Li m: = (0.0500)' (0.0500 (5)3 =— 1.089 KID-”ﬁg W1: :— 0.H‘-IO 32L ”:5 HngHﬁ‘b 4— 20’ ——v ZHgLQ) + 2011095) 5°:- +0.27v AGE-'- ‘hFEO 7' 2136?: (07%) ~AGE(H5\$C\H\$) AGHCJ '; cub) = AG£°(H%LCJ;.%3 “'nEEO '2 AG: (Cl: (119 3 ’ “0-7 l551ml" ' (ZmolXQWBEC' mo!” X 0.27 V) 2. 0 “Wm: |C= lT/v AG+LUT “b3 = “mm IJ-MOI" 0,109+ HH+(wb\ + L”; —=; mom 5°: [.1qu “Of 1* 50 E : 5°" ﬁgﬂ“ ZOE may 0700 _ __ 8.3H'S'Mol'l K'XZ‘MJSK l __ 5' "71W ‘fXQMescmorO ’3‘” Wow ' mo" 11.6 comhmted to) am: )LilmH+ -— (0.717)(o.7oo)= 0.507. , W ,1. = LZHV 5417/0“! HYQWBSCMDI") “(v-6013* HMSHUC MOI" Z MXIOOO/o 1:: ‘Ojl‘lo/o LLHV Oxidaﬁom = EMS) 4' EmHmb) 4— 1e: 5°:O.7Lol8V Wow 1 Cuﬂ€acb3+ 26" ——=7 01(3) 5°: O.?>?>7V Overall '- ante) mammaszznnabﬁcug) 5°=Loqu LOVICW 04,:MVM0 , V (B.5IH3'M01"|¢"2(736.I5I¢) O-IOOM°1"‘5'/Mo 50:11 5 1.095! ’ @XQU‘wEC/mol") 5——ﬁ—,wom,.kﬂ.. M Eu,“ 7' I.H‘?\/ . when 61.; ‘- 7/; G13?) _ - 1- - —. - (55H T-mol llc‘lgzqmsgb o.l§o)(o.log) Mo Ed" LOCHV (2)chan mot") Q W Ea": HOBV Edaﬁua (mu-DP l-ll‘iycga'gﬁoav HOOD/o '= I093 m TD hbercd'e 1n cho ,-Hne Po“ “nu/5+ Jake 5W1? 305 mounts FGQChom H" (rub) +6“ ~37 J; H45) E°= 0/) (13+: Ltd J? Ox + e E°=7 Ouarall= Wing) +uoL—J? -‘5:H2(5) HM matted 04%;! and via—=1 , 5:50:0V For 44/16 ouemu read—ion +0 «framed as wwiﬂfn, 53mm“ mac-9+- be >0 , 60 55mg mwsk bc <0. We: redox reacﬁon 'Is Omar—=7 126d HM cox/111' muﬁd : 43+qu For Hat: overall rmﬁm +0 be wovHaWwLLsﬁWor 0x+e'-=7V.ed muser be >0HIHVG°WM He H*' reacﬁoﬂ). Im oﬁaer words, (5me <DHIHV C) mjdro en 1% 0L beifer redmﬁm 0.36%!— lamb eoluuh'om W66 ﬁne mam—gm ?0+3V‘Yl'l‘1l WCOF «Hm; Jinlg) —» H+(a%)+ a“ PeacﬁOV) becomes more 1miﬁuc as Hm: TH decreases. at) MIDDHC'Q + H2000 + e: A? Nitorr),,© + OH'lmb) 5°: mew Hon-(cub) —‘7 07,053 + whoa) We: 9:49va Overall - H NiOOH(53 + 2mm!) 4» LINMomzts) +0165) 5°: +0.1” QnK _-.. 07': 50 = (QXQWQ Quad") V2 5 =- 50 "' E .040 (aﬂz)... :: ’Oowléoﬂbﬂlo ((01-7) ILT (9.5M x-Moru.,¢-e)mg_,5© (O-IH V) -.—_ (3-5 Kr— L05 % II)8 1») maﬁa?) + 4H+(aq;) + 5e: 4? N003) + mama) 5°: mamv 2mm 4207,th + 4H+la® we: 50:4.mv Overall: HNOJCQQJB + HHdcub) -? HNO (:5) + 2mm) + 30,159 B°=-o.uzv ; v1? c: (quwas mo" - __ MK 1275 Wt ”71"” ”7‘ 14-: (am x 10’5“ ...
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