Practice test 1 - Dr.Malgorzata Deyrup All rights reserved...

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Dr.Malgorzata Deyrup. All rights reserved. Copyright Department of Chemistry University of Florida PRACTICE TEST 1 CHM 2211-0787 Fall 2009 Name:____________________________________ UFID#____________________________ 1. (20) Write structures of the immediate precursors (last step leading to the product). Aqueous workup will not be considered a last step. OH OH O a. b. CH 2 c. OH d. CH 2 NH 2 2. (20) Write step by step mechanism and the product for the following reaction. Make sure to show all the intermediates, and indicate with arrows which way the electrons flow. Indicate where the labeled oxygen will be in the product (s) H O 18 OH + CH 3 OH H + 3. (20) Write the product corresponding to letters (A,B,C and D) for each of the following reactions: 1
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2. Ph 3 P=CH 2 A B C OH 1.PCC MCPBA/CH 2 Cl 2 HC C D Hg 2+ /H 2 SO 4 H 2 O 4. (25) Design a synthesis for the following compound. You can use any other reagents (that contribute no more than two carbon to the final product) that you need to accomplish your synthesis.
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