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Reading_for_week_3 - of spectroscopy 2...

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Reading for week 3 ; Chem. 127/227, Fall quarter 2007 To assist with what is or will be discussed in class, read the articles numbered 1-3, below. Reference 4 is an important publication. It’s not imperative that you read it in its entirety at this time, but be certain to be aware of what a tremendous source of information it is; note especially the vast collection of important rate data and the relatively complete discussion of radical clocks. This paper, for example, contains the rate information that was used in class to illustrate how one decides on the concentration of tin hydride to use in radical cyclizations. formation and detection of the cyclopropylcarbinyl radical 1. Kochi, J. K.; Krusic, P. J.; Eaton, D. R. J. Am. Chem. Soc. 1969 , 91 , 1877 an ESR (aka EPR) primer – read this one to learn the basic idea of and uses of this form
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Unformatted text preview: of spectroscopy 2. http://en.wikipedia.org/wiki/Electron_spin_resonance#EPR_applications clock reactions 3. Griller. D.; Ingold, K. U. Acc. Chem. Res. 1980 , 13 , 317-323 4. Newcomb, M. Tetrahedron , 1993 , 49 (6) , 1151-1176. If you have the time and want some additional reading, here are a couple of references that are relevant to what is/has been covered in the lectures… The synthesis that was used as an example in class Lee, E. etal, J. Am. Chem. Soc. 1997 , 119 , 8391 application of clock reactions to studying enzyme processes (one of many, including many of much more recent vintage – it’s a widely used technique. Use SciFinder Scholar to find additional articles) Ortiz de Montellano, P. R.; Stearns, R. A. J. Am. Chem. Soc. 1987 , 109 . 3415-3420...
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  • Fall '09
  • Chemical reaction, American Chemical Society, radical cyclizations. formation, relatively complete discussion, important rate data, D. R. J.

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