3,4 > 8 > 5,7 *Kinetic factor OH-O-C-(CH2)5-NH2InitiationH2O +(CH2)5N HOC(The major reaction is the monomeradded to the growing chain, resember to the chain polymerization. However, some condensation reactionbetween two linear molecules is also possible, which is only minorcontribution to the polymerization)kpn+OH-O-C-(CH2)5-NH2PropagationHHOOOxH-O-C-(CH2)5N-C-(CH2)5N-C-(CH2)5-NH2(CH2)5N HOCThere is no termination step. The reaction kinetc is very much similar to the living chain polymerization. [I]o[M]o-[M]tXn == - kp[I] [M]d td [M]Rp=Homework 7:
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This note was uploaded on 10/16/2010 for the course MATSE 441 at Penn State.