Chap._900009 - 3,4 > 8 > 5,7 *Kinetic factor...

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3,4 > 8 > 5,7 *Kinetic factor O H-O-C-(CH 2 ) 5 -NH 2 Initiation H 2 O + (CH 2 ) 5 N H O C (The major reaction is the monomer added to the growing chain, resember to the chain polymerization. However, some condensation reaction between two linear molecules is also possible, which is only minor contribution to the polymerization) k p n + O H-O-C-(CH 2 ) 5 -NH 2 Propagation H H OO O x H-O-C-(CH 2 ) 5 N-C-(CH 2 ) 5 N-C-(CH 2 ) 5 -NH 2 (CH 2 ) 5 N H O C There is no termination step. The reaction kinetc is very much similar to the living chain polymerization. [I] o [M] o -[M] t Xn = = - k p [I] [M] d t d [M] R p = Homework 7:
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