RelativeResourceManager (3) - CHM 2120 Assignment 3 In this...

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CHM 2120 - Assignment 3 In this assignment: - Electrophilic addition reactions - Radical substitution reactions - AntiMarkovnikov addition to alkenes - Syntheses - Drawing and naming aromatic compounds - Drawing resonance structures involving aromatic compounds - Distinguishing aromatic from antiaromatic compounds Note : Some questions were taken directly from CHM1321 assignments. You can choose to review your notes from last year or repeat the assignments. 1. Provide a mechanism for the following transformations (only product is required for h and i): H 3 PO 4 H 2 O (solvent) H 2 SO 4 H 2 O (solvent) AIBN Δ AIBN Δ + HBr a) b) + HCl c) 1-methylcyclopentene d) e) + HCl f) + HBr 2. Explain the formation of the major product: O CH 3 OH (solvent) O OCH 3 O OCH 3 H H Major very minor H
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Assignment 3 2 3. The natural product nerol when warmed with acid leads to a number of cyclic products including terpineol and terpinene. Explain the formation of these two products from Nerol and the isomer called geraniol , where the double bond at C2 has the E geometry are the major constituents of rose oil. Terpineol and terpinene
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