POD01Key - product is formed in the reaction draw it in one of the boxes and fill the other box with the symbol “X” If no reaction occurs under

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Problem of the Day #01 – Answer Key Deadline : IN CLASS on W 7/14/2010 LATE WORK WILL NOT BE ACCEPTED OR GRADED!!! This problem is worth a total of 20 raw points. Each part is worth 4 points. In each part below, predict the structure(s) of the major product(s) that will form when the organic starting material is subjected to the indicated reaction conditions. If two different products are formed, draw both of them, one structure in each box. Be sure to show any stereochemistry clearly and unambiguously in each structure you draw. Remember, stereoisomers are different compounds! If only one
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Unformatted text preview: product is formed in the reaction, draw it in one of the boxes, and fill the other box with the symbol “X”. If no reaction occurs under the indicated conditions, fill both boxes with the symbol “X”. (a) + Br 2 , h Br CH 3 H 3 C Br (enantiomers) (b) + 1) BH 3 2) H 2 O 2 , NaOH, H 2 O OH OH (enantiomers) (c) + 1) Hg(OAc) 2 , H 2 O O 2) NaBH 4 3) CrO 3 , H 2 SO 4 , H 2 O (d) + 1) Na (2 eq) in NH 3 ( l ) 2) OsO 4 3)NaHSO 3 OH OH OH OH (enantiomers) (e) + 1) mCPBA (a peracid) 2) CH 3 OH, H 2 SO 4 (cat.) OH OCH 3 OH OCH 3 (enantiomers)...
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This note was uploaded on 10/25/2010 for the course CH 310n taught by Professor Iverson during the Summer '08 term at University of Texas at Austin.

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