POD03Key - DIASTEREOTOPIC CONSTITUTIONALLY NONEQUIVALENT...

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Problem of the Day #03 – Answer Key Deadline : IN CLASS on F 7/16/2010 LATE WORK WILL NOT BE ACCEPTED OR GRADED!!! This problem is worth a total of 20 raw points. Each part is worth 4 points. In each part below, determine whether the circled protons are homotopic , enantiotopic , diastereotopic , or constitutionally nonequivalent (i.e., a “substitution test” would give constitutional isomers). Circle your choice. No explanation is required. (a) C C C C C H H H H H H H H H H H H HOMOTOPIC ENANTIOTOPIC
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Unformatted text preview: DIASTEREOTOPIC CONSTITUTIONALLY NONEQUIVALENT (b) C C C C C H H H H H H H H H H H Cl HOMOTOPIC ENANTIOTOPIC DIASTEREOTOPIC CONSTITUTIONALLY NONEQUIVALENT (c) HOMOTOPIC ENANTIOTOPIC DIASTEREOTOPIC CONSTITUTIONALLY NONEQUIVALENT CH 3 H H H H (d) HOMOTOPIC ENANTIOTOPIC DIASTEREOTOPIC CONSTITUTIONALLY NONEQUIVALENT C C H BrCH 2 CH 2 H CH 2 CH 2 Cl (e) HOMOTOPIC ENANTIOTOPIC DIASTEREOTOPIC CONSTITUTIONALLY NONEQUIVALENT C C C C CH 2 CH 3 CH 3 H H H H H H...
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