H03- Atomic Theory 2 - saldana (avs387) H03: Atomic Theory...

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Unformatted text preview: saldana (avs387) H03: Atomic Theory 2 Mccord (52385) 1 This print-out should have 22 questions. Multiple-choice questions may continue on the next column or page find all choices before answering. Here are more questions from Chapter 12. You should really work far more problems than are here. Work problems that are at the end of Chapter 12 - there are over 100 there and you can check the answers on half of them (the odd-numbered ones). Also, a reminder that our first exam is on Wednesday, 2/10, from 7-9 PM in WEL 2.122. 001 (part 1 of 3) 10.0 points What is the principal quantum number for the orbital 5 p ? 1. None of these 2. 6 3. 4 4. 2 5. 3 6. 5 correct Explanation: n = 5 002 (part 2 of 3) 10.0 points What is the orbital angular momentum quan- tum number for the orbital 5 p ? 1. None of these 2. 1 correct 3. 2 4. 4 5. 3 6. Explanation: = 1 003 (part 3 of 3) 10.0 points How many magnetic quantum numbers does the orbital 5 p have? 1. 1 2. 3 correct 3. 7 4. 5 5. 9 6. None of these Explanation: 004 10.0 points How many total nodal planes are present in the complete set of 3 d orbitals? 1. 5 2. 3 3. 16 4. 20 5. 10 6. 8 correct Explanation: There are 5 orbitals in the 3 d set. 4 of those orbitals are cloverleaf-shaped and have 2 nodal planes each. That combines to give 8 total nodal planes for the set. The other (5th) orbital is the d z 2 orbital which has 2 nodal cones, not planes. 005 10.0 points How many nodes are present in a 3 s and a 3 p orbital, respectively? 1. 0 and 1 saldana (avs387) H03: Atomic Theory 2 Mccord (52385) 2 2. 2 and 1 3. 0 and 2 4. 1 and 1 5. 2 and 2 correct Explanation: A node is a point, a plane or a three dimen- sional region of space where the sign of the wavefunction changes from positive to nega- tive, (or negative to positive) so it equals zero. The lowest energy s orbital is 1 s , and this has no nodes the wavefunction is always posi- tive. As we go to the next higher value of n we add a spherical node, so 2 s would have one node, and 3 s two. The lowest energy p or- bital is 2 p ; it has one nodal plane which cuts through the nucleus (the two lobes have op- posite signs). Again, as we go to the next higher value of n we add a spherical node, so a 3 p orbital has two nodes.orbital has two nodes....
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This note was uploaded on 10/25/2010 for the course CH 302 taught by Professor Holcombe during the Spring '07 term at University of Texas at Austin.

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H03- Atomic Theory 2 - saldana (avs387) H03: Atomic Theory...

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