Chpt 7 Solutions

Chpt 7 Solutions - CHAPTER 7 ATOMIC STRUCTURE AND PERIODICITY Questions 19 The equations relating the terms are = c E = h and E = hc From the

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212 CHAPTER 7 ATOMIC STRUCTURE AND PERIODICITY Questions 19. The equations relating the terms are νλ = c, E = h ν , and E = hc/ λ . From the equations, wavelength and frequency are inversely related, photon energy and frequency are directly related, and photon energy and wavelength are inversely related. The unit of 1 Joule (J) = 1 kg m 2 /s 2 . This is why you must change mass units to kg when using the deBroglie equation. 20. Frequency is the number of waves (cycles) of electromagnetic radiation per second that pass a given point in space. Speed refers to the distance a wave travels per unit time. All electromagnetic radiation (EMR) travels at the same speed (c, the speed of light = 2.998 × 10 8 m/s). However, each wavelength of EMR has its own unique frequency, 21. The photoelectric effect refers to the phenomenon in which electrons are emitted from the surface of a metal when light strikes it. The light must have a certain minimum frequency (energy) in order to remove electrons from the surface of a metal. Light having a frequency below the minimum results in no electrons being emitted, whereas light at or higher than the minimum frequency does cause electrons to be emitted. For light having a frequency higher than the minimum frequency, the excess energy is transferred into kinetic energy for the emitted electron. Albert Einstein explained the photoelectric effect by applying quantum theory. 22. The emission of light by excited atoms has been the key interconnection between the macroscopic world we can observe and measure, and what is happening on a microscopic basis within an atom. Excited atoms emit light (which we can observe and measure) because of changes in the microscopic structure of the atom. By studying the emissions of atoms, we can trace back to what happened inside the atom. Specifically, our current model of the atom relates the energy of light emitted to electrons in the atom moving from higher allowed energy states to lower allowed energy states. 23. Example 7.3 calculates the deBroglie wavelength of a ball and of an electron. The ball has a wavelength on the order of 34 10 m. This is incredibly short and, as far as the wave- particle duality is concerned, the wave properties of large objects are insignificant. The electron, with its tiny mass, also has a short wavelength; on the order of 10 10 m. However, this wavelength is significant because it is on the same order as the spacing between atoms in a typical crystal. For very tiny objects like electrons, the wave properties are important. The wave properties must be considered, along with the particle properties, when hypothesizing about the electron motion in an atom.
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CHAPTER 7 ATOMIC STRUCTURE AND PERIODICITY 213 24. The Bohr model was an important step in the development of the current quantum mechanical model of the atom. The idea that electrons can only occupy certain, allowed energy levels is illustrated nicely (and relatively easily). We talk about the Bohr model to present the idea of quantized energy levels.
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This note was uploaded on 10/27/2010 for the course CHEM 102 taught by Professor Peterpastos during the Spring '08 term at CUNY Hunter.

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Chpt 7 Solutions - CHAPTER 7 ATOMIC STRUCTURE AND PERIODICITY Questions 19 The equations relating the terms are = c E = h and E = hc From the

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