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chem3331-bean-05 - Simmer 5 §£egaachem§siry £391 £33...

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Unformatted text preview: Simmer 5: §£egaachem§siry £391- £33: flflMSYWQfiQMAL S?EREQ§SGMER$ {Simsturai} Same farmuia, same cameatévétyx Same iarmuia, am. canneciivity diff. spatiai arrangement CQN¥§§£§§§AfiGN§£ QQNFGRMA‘RQfiAL Cami}: be? miercmvefiezj amass Ragidiy érzfez’canvmed mads are Makers wiimut bfeakéng beads»; Can be ésoiatesi Can’t be ésaéateéi {usuaééy} Carmnmmmfi séngie band Amine miatém swimmers Envefs-ém Cmmrmers I i EfiAMTmMERS fiMfiYEREGMER$ Mifmf imagés that are Ceafigumfimai ésamam that are m: mérm; newszzgerimpasabée émages {irzsiudas aigz’irans ésamars} wentifyifig chirai cemem: g“? H ”i. E g; .C ,,,,, £55358? Bguiw‘“ \ CV“ ‘ v W3; \F F 2‘” {EH3 2. CifisCHECHQCHfiHzm{EmCHgQHEQHZCHCHS H H36 CH H x ’l H Hggx /\ H g H 63‘“ L FISH?) Assigning BIAS : é{32132:},x’3ng03{iffireiag {Semremmns} I. Asesfzgn prieritiea {1,2,3,«5¥-,’: {:3 the fear groups: 2123;216:253. m the 3temo€emer based on ammic number {highest atomic #12:}, anest awmic w j}. in the 62235 a? isompex, the. isotope c-f greaier mama gas pfiority: Z 323. the {raw of idemicai mama attached {a the siemmmm‘er, {examine me maxi sat 0f mama Armn gc mama within each sat in girder Of highest to iowas'z.‘ pfimfiy 01311;)ng the 5:325 and aasign {ad-am}! at the first point of aiifferemxa 3. My groups :‘zc33‘ztairfi13g dmlbk‘. m high bands; the gamma {if the muitipie hand are dupiicated or tripiicateed before. £1.33: gning pfim‘ii}: 4. Mia: aasigmng pricifitiex, mute: the: xtmmure 50 that {the haves: prmrity gmup {4} 1-9 directed away firm: the viewer, fimw an WGW fmm 3 m 2 m 3. if the arrow is sriockwise, the assignment is iii, if the: anew is counter ciaxtkwige, the awignmeni is S Iii“) Pmperzias a}? 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Wham determining Chiraiiiy in systems that exfigi as rapidiy iniemmvefimg (swimmers; iaak €05 mama; {3? gymmetyy fig: 291% mast symmetricai {egresematian 0°? the maieguiev rings: CH3 ”F/XLSH m:> 2’ 3 ”W“ rig: acyaiin: i Maégggiagmmmgm_ih_a{:__§)na,Sfiammemej §f EB? Passébie # a? atereaésamefs z 2“ CfisCHfifififichg r: m # :3? stareacentam Qfig Hm if: «“8? 3 Ha» {3 MB? Emma-g §r $2“ CH3CEH~CH€H3 QH?» Sywiémfi fiwC MB? CH 3 Mega cammuncfi: Naming cemgwunda with mam than {me stareacamer: QHS Brw-{EWH 5 E Has» {3 m8? 5H3 ii} §§S€§EER ”£3R{},§E€ZTE{}NS ~ Amaiygmg 313 maiemies (32:: a fiat gufface ‘1. Main carbmta Chain. is verijtai. 2. Vertica} fines repregem bonds; behiim @3338 {31% dasheg} 23;" in. 3323121222. 3. E-igrizemai fines represem mafia 1:1 from 0:" flame {mag wedges}. 4. Zniersactémm represses: Chiral carbon, a‘iOfilfi. 5. M032“ exigiized group is ummi’iy places? at the map. 5. Figrzhaér pragetztizmg must :30: be mmm’eé {mm 3:216: flame 0f the paper. (The; 6212131101: be: picked up and flipped mam 7‘ Projections may be matted. in new ways: 1} The wha’ie pmiectien may be {mated it}; 180“ GNifz‘i 2} One gram}: attaihed m a. chiral {faréyon may be Eaveid Miami}? mm the {Either three gmupa may be mated chemise or ccmmercieckwisa fismm Examgaéas Qfis Bfwéimfi ngwfir 6H3 QQQH QQZH Hw—{i‘szH WWQMH aHE EH3 {sag HGW‘WH (332% {:2 {3; Fmgms-é {arm mz-a Br F {SHQCHg CH3 83"“ “H arm wE—i H” “”8? Hm MB: {3&3 CHECHS CHQCHg, {Emmi fiampmms Wimmi Shim; Mamas 1‘ wgiawées mm are ”baked” 5am asymmeigia mafarmafians: /’u~'>c=’r “‘5. 1 . ' ‘ j. . . V $553" 2 394233;. } a ‘- 53. x / fwx UNA-l ........ J 8?. , RM... .\ \ "1, \\ I ‘I X \ 1‘ \ //;""""""\x 1/ $4 [3/ \ \ ’ \.... /): ‘ \ \>_,.“,_...(‘.f \j / Wm ‘ x /' ‘a / 2. Sumi‘éiumcfi aiieneg: Amgéuia vg Reiative Qamfigumiim gag , 9H3 P QHS ngmCQfi WC)“ fimg-«CHyQi-é $3 HwéwCHQ-xfis’ CRECHQ, CHZCHS éHQCHyR mm QR?) wwgwcaya CH2€3§-E3 ...
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