IUPAC and stereochemistry

IUPAC and - STEREOCHEMISTRY PROBLEM SET 1 Give the complete IUPAC names for the following compounds a Br OH OH b CH(CH3)2(CH3CH2)2CHCH2CH2CHCH3 OH

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STEREOCHEMISTRY PROBLEM SET 1. Give the complete IUPAC names for the following compounds: a) b) c) d) CH 2 CH C 3 3 HOCH 2 3 2 CC 2 2 3 H 3 2 CHCH 2 3 H 3 H 3 2 3 3 3 3 HB r r Br C H 3 C 2 C 3 OH 2 3 H H Cl Br 2 2 3 2 2 2 3 H CH(CH 3 ) 2 3 (CH 3 2 ) 2 2 2 Br e) f) 3 3 2 HC H 2 2 g) h) 3 ) 2 3 2. Draw the following structures: a) the Newman projection for the most stable conformation of (2R,3S)-2,3-dichloropentane b) the meso isomer of 3,4-hexanediol c) all the stereoisomers of 1,3-dibromocyclopentane d) the optically inactive steroisomers of 1,3-dimethylcyclohexane
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2 3. Label each of the following pairs of structural formulae as enantiomers, diastereomers, structural isomers or different representations of the same compound (identical) a ) CH 3 3 Br H H 3 2 H Br 3 3 3 2 H b ) Br 2 3 3 H H HO 2 3 OH H 3 Br H c ) 3 H Cl I H 3 C H H 3 3 H I d ) 2 3 H 3 H 2 3 3 e ) 3 3 3 3
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3 4. Determine which of following compounds are chiral g) a) d) b) c) e) f) CC C Br H NO 2 O O C OH 2 C HO CH 3 N 3 3 H C H 3 H 3 3 H Cl H 2 2 3 H 2 2 3 3 3 3 Br h) i) H 5.
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This note was uploaded on 11/15/2010 for the course CHEM 212 taught by Professor Harpp during the Spring '08 term at McGill.

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IUPAC and - STEREOCHEMISTRY PROBLEM SET 1 Give the complete IUPAC names for the following compounds a Br OH OH b CH(CH3)2(CH3CH2)2CHCH2CH2CHCH3 OH

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