01 - Solutions - 2 POM 41,4 Chem 112A Fall 2010 Problem...

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Unformatted text preview: 2.; POM; 41,4»? Chem 112A, Fall 2010 - Problem Set 1 Due in class on Sept. 21 . 2WD. You are encouraged to work in small groupsfor rhir assignment. Anne—r Kay '-"_"—I_—.n.i_._.II | . Provide correct IUPAC names for each of the following compounds: :1. M 1.3-1“ “moi Pkg“ '3' ’KC 3““‘1 l' 4" hit-“Lyl-l‘htkfihfi c. W F-G‘MYIL lag-Julmflrfl‘l—P'Iuht. d. vr/ 4*rlsn’proprflula'hne 44" q“0"‘l¢1grffii‘£fl) ch'l'qu: e. W F'flfirf- aZ-Jlflflylnflnau 2. Fmvidc accurate line drawings for each of the following compounds: 3. 2,2,4-Lrhnctnylpcnrnne X/K b. 5-hoty1dccane W c. 3-rerr-botylpenrane d. 5visopropyl-2.2,4.o-tctramcthyldccanc WV 3. Draw all possible isomers for {25qu and provide a com name for each. Be sure not to include any dupli- cate compounds . and do not Wflrfl' about using wedges and dashes in your answer. n»- lacmu c. ., 2 “wl'LHPtI-c'hnc 3-wL Z'Z-noi: [ ‘M‘M Lance. '“ 1 - . /K( i ‘3 0‘: Mari Lq‘llq .q in All. “A“; 4. Draw Newman projections corresponding to all of the eclipsed and staggered conformatiuns of vaethyl- butane. Use numbers. to rank the energy ef each conformer, Iwith l repreaenting the lowest etterg},I species. nib (at £1». 2—: Lot—‘01: Q... :fii: Q; :fiét “3129i: 120 I 59 ;:¢' ® (:9 GD 6) G) a) t 44.9: 3 t—--l-1ml.-————T 5. Identify all of the functional groups in the fulluwing molecules 2?}? W audit-4 (nu-tit... at.) 15. An trainer is a special type of amine that has a carbon-nitrogen double bond. Ccnsrruct an orbital interaction diagram that compares a carbon-nitrogen double bond to a cathcn-exygcn double bond on the same energy m. “e... w. “an H emmm “we" . "L H 11 Fl 15 More cite-430%“: {CF-Hh imine ketcne h 6"" "7.50 7-H": H’ cf“- .vll-ii“ * "I II * p 313 1'“ P 4”,” “‘13“ ‘P ‘ {a “1—... ‘L a a , n we .. r :9 :5 ‘P‘ "‘1'“ II Edi-why”? H” H' “ 4. 1". For each of the fcllcwing compounds. circle the MOST acidic proton (you may have to draw it in1}. Briefly explain your answer. ftimfififlt. c-H-l‘iid-‘m: = \ “P'l‘rm‘fi‘ma earl-w )‘i‘fiD e are More clad“ .p g' H 53%“ c “‘3‘“ '" H : JYH H h D 3. Which of [I]: falluwing pairs of structures are related by momma? Y amalgam" Lafifi H H N ”CIHQ d.>l,tq—'a- alto-as until." {Haws may a a a 0,3. H Itefi a; a b. (9? .H. ‘9 VIE? by?) ‘1'? e "W”; H wok H kl Feat) ...
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