Practice Final - Chem 109A Practice Firm 1 Give The major...

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Unformatted text preview: Chem 109A Practice Firm! 1. Give The major produc‘rs of The fdiiowing reacfions. CH3CH2CH2CECH W 2. HOTH202,H20 CH3CH2C;=-_—CCH3 + H2 3-959.»- H2304 CH3CH2C ECCHQCH3 ‘ + H20 M CH3CH2CECH + HBI‘ W EXCBSS . 3% Cflzmtl‘HCHZCHszCHZ + HBr _..___..__,.. equivalent amounts of each reagent For the next '- 4 1 reactions, Show the configuration of the prodijct. Pd/C .‘ Lindiar catalyst C-H3CH2C ECG-I3 + H2 CH CH CECCH + Na mum-nu» 3 2 3 NH3(liq} CH3 ‘ I C CHSCHg/ \“‘H B: 4* CH3 OH ---——----> (3., I + CH30H M3 - c: 0 CH3CH==CHCH2Br + (33130 M . under conditions that favor an 8N2 réaction. under‘ conditions that favor an 3N1 reaction. an; . ow) {3r "0 - “43> CH3 W ._ * 5 on 0+3m'“?H-*CNL*U“3U+Z v Ev 393 3 Br 0 d H > 0”.3 ON / -l A IN ~———-—-——> M ‘ ON (we 4 l M> 2. Name each of the foilowing: a. CH3eHCH =CHCH2CH :CHCH3 01. CH3 ‘9“ CH3(IZHCH2CH :CHCHZCHg OH H (Long 2. "‘wz—chacu on 3. Give The mechanism for the foliawing reactions. H-‘mBr CHgCHflH HCHmCHCI-Ig mm» 4. Draw The com‘ribufing resonance s‘rrucTures for each of The foiiowing. + a. UCHZ ' 6CH b. g" 3 O H /C\ H 1 H3C CH—uLHZ 6- CHg'mCH ~CHiH M13114; 5 Using The given s’rar'fing ma‘ieriais and any necessary reagen‘rs Show how each of the foilowing couid be synthesized. O H CH3 CHzc %H W CH3 CH3CCH2CH2CH3 i HC ECH “my... CH3CH2&H _ CH3CH2 \ H CH3 CHZC ECH -————--h~ C =C/ H/ \CH2CH2CH3...
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