Ch06_InClassProblemsExamples

Ch06_InClassProblemsExamples - Enantiomers 2-B u ta n o l...

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1 Enantiomers Enantiomers 2-Butanol has one chiral center here are four different representations for one enantiomer using (4) as a model, here are two different representations for the enantiomer of (4) H 3 C OH CH 2 CH 3 H (1) H 3 C OH CH 2 CH 3 H (2) OH H (3) OH (4) OH OH Enantiomers Enantiomers 2-Chlorobutane C H 3 CHCH 2 C H 3 C l C l H C l H 3-chloropentane
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2 Enantiomers Enantiomers 3-Chlorocyclohexene Cl Cl chlorocyclohexane Enantiomers Enantiomers A nitrogen chiral center N C H 2 C H 3 H 3 C N C H 3 C H 3 C H 2 A pair of enantiomers + +
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3 Problem Problem Which structure is different from the other three? A B C D F H H 3 C Br Br H F CH 3 F Br H CH 3 CH 3 H F Br Naming Chiral Centers Naming Chiral Centers ( R )-3-Chlorocyclohexene ( R )-Mevalonic acid 2 3 R 1 2 3 1 R Cl H HO OH O HO CH 3 1 2 3 4 1 2 3 4
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4 Problem Problem ( R ) ( S ) ( S ) ( S ) ( R ) ( R ) ( R ) ( R ) Which structure is different from the other three?
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