CHEM 230 Problem Set #11_key

CHEM 230 Problem Set #11_key - CHEM 230 Problem Set#1 1...

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Unformatted text preview: CHEM 230: Problem Set #1 1 Additional Coordination Chemistry Problems Textbook problems: 21.4, 21.5, 21.6, 21.8 Additional problems: 1. Given that [Co(H:;O)6]3+ is low spin, explain why it is possible to predict that [Co(bpy)3]3+ is also low spin. (gave—A 0’“ ‘HA‘ S'P’écl'chra-oo Sofie—g ‘. Brbé Fh— é CDl—lfl‘allLOc \)H7D< [cu‘] a} Car Comedy brash“ Wool €154“le slab. to) [arcmmgjfi‘r similar, Rena lama 6) [Fe (“3113" \mi‘l/ur m-Lal axiéqlma slab; A.) [Nzcenxj smarter Rad llama a) tee FLT“ s“ («M imam Mel , one «51:10er P) (695513“ 2nd Vow +r‘msll‘i‘on GD l® Camus“ 4"" 4— 3r 4% 4L— 5H: on W. w +0 AH aim-wag gr 0/? no CAKMLL J c1 / ~ ’ 56W M 0"" 57”" ® OcLaLxectch GILt 4— "— fl — + 4 + 7% y— 71 5/0"" /0w S/oi'n ngf‘éflté‘. iguana/5 an WAIZA con/guradl/‘on gas AW 3 77/3 9917/ 5.4 AQKC/ on. IVIL is he Faizéé 4‘0 frame—t2 an gag/@4710 7%; ej 3—444 (pf-x Parr- 7LAa QQCJZT'o/x ft": "/1727 5/DM ADC-1L < [0 weak /ow S/OI’A 430C;— >P 5/7017 fia/d @ Maj/\ezfi; Sosa/oxyéf/fy #5 n=’—/ u/ypafnec/ es“ L S I): Z arm/earned es“ 5., @ EMA(CN)67Lf- z.) Mh2+l a/ I /0w S/OJ‘A (D [Mn(cN)6—]Z' (3) =7 Mn“)c/3 ho oMé’m/nm. Au!an .— _—— 42—4—4— [Moog-‘75) => a“ 0/5” gyz 5 m / 2 @ [PJ(CN)H:|1"(0)=? Pc/H/a/B/ SZUW f/maxr“ ® [cod/J? m => (a ,4? ,é/razza/ (ways/31 / W) ED WM?“ (2.) => Nr“ 0/9 Maw/MK @ 0F [5 6L 5%!an 0L5 7L0 5:0 {Se—e S/LLc/Lraclw Fca/ Sarfcs flus iF [co(/¢Zo)¢7%rs /ow s/om ) [co (6pj337y W,'// A; /ow Effn . ...
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