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CHEM 230 Problem Set #5_key

CHEM 230 Problem Set #5_key - CHEM 230 Problem Set#5...

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Unformatted text preview: CHEM 230: Problem Set #5 Textbook problems: 2.21, 5.10, 5.12, 5.]3, 5.14, 5.25 Additional problems: 1. Explain why CO acts as a ligand for transition metals through the C atom rather than the O atom to give complexes of the form “ M-CEO ” 2. List the differences between the M0 diagrams for BH; and NH; shown in Figures 5.17 and 5.19 in the text. Explain why these differences occur. In particular explain why the 2132 orbital on the central atom is non-bonding in BH3, but can interact with the LGOs of the H3 fragment in NH3. C. O C, O (Y {note ${2,2_ JiFCqu ‘ 1r w W C o c; O f. gflm/ gay/0 Draw 5% Sula—0n SH In kx'k‘ In Of‘cizr #0 Mc/ULa fl COM/0(1krpé 0F MO O/i‘ajr‘ms) LOO; CU‘C US$41 WMAJ 'fiLa l‘n‘ZC/‘Okc7zl‘ol’l5 461W écano/I‘n @M/DOW’LS M “LC/UNA #0 0k flflu,coM/00W7L fan: [OJ/W Tlme “Umw 0F— LGOS 1' “HAL HUMLZQA" 5P CLLOMYQ «3&3?qu U544 Sm BeHL eXM‘PLL C‘qlcula’bl MOS ‘Rr ”2,0 :7 O (Lu/IA L605 For H”H P=>[email protected] g“ £pr O——> _ / \ 3 W = @ W :7 W H j, u * @ @2 *- 0 @ z w = S; 7) @ @ “(L :7 8 @ @ 0L3 If plateau/la»:- Elm f5 XL.) I WCOT‘L W B '73 no Ml- owls»? haw “HAL {)3sz [y/ \H orbilnoi MA M an? M H {5 OVEHTAS 9°. 2P1 TS hon—\oom—mej 103’ 80 MI A60 m [SHE (1.,' or kt)‘ ,@\ e: or wt. 1L8} gang, Bonclm: /7 -/, ‘ 1 . 5 di%b w {Au 2?.) 6,20 ngkfi Charm—9: / \ I" @: did) 0% q...“ a 2": 2?: / Anklomlm) CL”: d8: _> not. mixing OF 2.5 in MO ‘ MA GIN fnlefix¢LFOA qucarm / LE} Nor-L M¥|Londffl3 ,, s ”O“ F] 2— C{)(3 #12" (6:0 7 Z ‘ H \ C’ '5‘“) C9 <-———7 Q C .. ,// \\ \ _.g/ \g 6 .0 o/ \ O 'L C- 15 SP 143 LMclimcl - Ckanxctxs 0‘; M03 in E3 L33") .3 3 CPQ fi‘loonéifi de‘ocaLizeL 0") CDML’W‘LM“ Of P7" &% over mu 02.41133 . 3% (unhbuhon From QPPOSQtI hon-benchnj b) y— P‘M‘ae- 2?; orBit-«Ls on O -am‘rl\oor\ n OFlO\IL‘O&L C) Q®%@O or 2P o “Quilts MA 23 c. A AJ“ Ll‘ome PWIJLLWLS ® [CE-'— 0'. Ac. 3 as a. Liam .1— is wosH CM‘DOHF Lama-a4 . FIT/NS “HA-L ken: PGCH‘ {Lid-vans 1-3 'Hm’s java-301 \uk Out. ova cx "cums Ease. €30. Cor‘ Lfnéinj #0 CL WUL‘r-cLK _ .Tlr—«s Is ofpcs‘tb. #0 Wkulr is ex‘axcffici bmscé on CLLLLT‘DM‘EALEV‘ILJ, A ‘HM‘OUflk C 0L3 -HI\JL HOMO (’30- 2.14 @ <23 bJPCeN/nm ‘09.wa 8H,: MA NH}, (5H3 = (fijonci P\0mcur‘ Nth}: +£33an PBmMEJCLgL =7 Tlru. lT MCI group orbit-“Ls, Fm— MH‘) AD ho‘t‘ fifl‘ 1““ ”HM. Same. Pkawxe ova ‘HNL N alum/IA) "Hus emu»? OF The. AO’S on N wi‘f‘k‘R/VL H LGO'S will he climax“? as Comfmé 4‘0 BR}. % % . (‘1) in Q SJQ 60mm 2')?- L‘ _..-—--—‘—_——“_-"__" N 2f)”- hon—bonAM 3 ‘oonAi‘a K 3 ...
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