CHEM 230 Problem Set #8_key

CHEM 230 Problem Set #8_key - CHEM 230: Problem Set #8...

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Unformatted text preview: CHEM 230: Problem Set #8 Textbook problems: 10.11a,10.lle,10.12,11.4,11.19g,14.3,18.2 Additional problems: 1. Describe how band theory can be used to describe the bonding in metals, metalloids, and non— metals. 2. Explain why alkali metal hydrides are less stable, and more reactive, in comparison to metal halides. 3. Define catenation. Why does carbon tend to bond with itself to form stable chain and ring compounds? 4. Draw resonance structures to explain why in N20 the N-N bond order is 2.5, and the N-O bond order is 1.5 5. The trend in bond strengths for Group 17 diatomics is as follows C12 > Brz > F; > 12 . Rationalize why the F-F bond is not the strongest in this series. 6. Explain the trend in boiling points for the Group 18 elements. r . Qfiz 1/ a'x'fif'" (— sf Lilla/l) ) Jl/ 610.959 .5 O rm: 6.7L Ma ’1 ZHZO ——> 2H1 4— oZ . 8 cf c—e H1 gran-«(J at“ CCuILAdQ M *10' COM Au: “lira-n OF #1 I .- —-> FQC/I‘Ccu/ flechA‘o/‘r 2/13 + O, —-> zulo _, W»me My“ Wows (gaunf) @JZ) #201 ——> H10 + f/ZOL xer/zaztcfijiwg 7:) ka‘MlLfcaJ/J fi/aéJCQ—a , ‘4'I'JT‘WJTCM ems 77$ :7 Add a. “.5954 (A440,) 7L9 Spud up macém éj frovidihj ,/ war {.Ae'rkyw af‘Aww. _ ‘L D c w /0 J (D [Ali finc/ In {Me/71M? P0171715 and f; gr meta/5 a) We filmy fem 715 => All relax/11MB /Ow => Weauk M'M bonO’fn )on/J one VOLme e.LL¢.“Po-r\ PeJ" GAR \ 1‘1") T‘) A“ are E:ch lath-L15 03,833 so C5 r3013“ ['70 l k are non— c.\cfi9.;— PuCkeé --_> AOwfl areur M—M bonéin bacon/~13 weaker, V‘WBvW‘B DNV \a’fin [355 Corb‘A’E-Lb NOW A ; $11.75 m F4. 3) Increusfncx cocrrfofl size“ clown (AWN-1F =- \ - " L/u-e Nov-0.. down ck” > Mt; 9473,94“ 4;: L? H. [9 Ho/ 5 {5 0F a wee: as NCLCI =7 Era/£41». Promss Férmqk‘on bF 0w: Cffi AnoC‘La.‘ 2c: m1.) —) Chen—P 23 QLJ’I/xodcf ZH’locz) 1* 26— -—7 2 [OH] 24.3“ 5mm 013 (TWA-Q \W - SPUCLU'VL \A fi/ Q) mafia, Acne/m Mam ham ’ M: W m Lam m aloLe, :Lo 61:- PCT-57L owl amoTl’LmJ" GS) ECLCA’D (leg 1‘) abjfij A? C.D’)C./u¢1L \ - 1‘") €>d€n5iv£ 77" Aondjfnq In a (ecmA C. is 5/31 Fesu/%s in ConJuLH‘vf/y alt-3,13 m 23+ be;in L'Q’a/MS . éj . C(dl—am.‘°{) -—"'> chr7lhfi) 363-: -—Z.‘) kT/Ma( :7. *F 14:11, yuan/Ma film’s ) j 070 L9. => BUT— dn‘qMancJ F5 Mow-e O/MSAL (fir—c. PaLcAJ‘hj) L) 3.51 s/cms vs 21.3 SAM-s p0,. akafiZ => Aa— wax mems dt‘mmonci WM 5&th 1) VSCLUSLWRI.‘ A l {Ame-rt s I r“ 'H'u‘s yum-*3 . \. \ / r +- \ He 347‘ \% He. He q_, fl He \ /// // \ ’Eonclm \ LH" M03 1% 3 N0 [50“ 22227—0 $011420? 2.. T E; #62 50“ Aondl'j and anrzr‘éonofl'hj M05 awe fi/QJ) 7‘5“; £044 orcéu- is 2.2m. 7205 #35 (€wa exfs/‘s as a Monmlom'c. as (He). [74627+ Am; a Acne! orchLr 0F 0.5- and Huus' Com 36 fillet-.414. E; 11m C212; gens a) #949!“ com (ax/glam $5111!be Ares (COHJUQAW’ ) CF WA//0foé) GLAC/ nonzmAZS/Ml 5 —-—~ M OF' MOS ____> My. 61/ M05 2) gézL/Tons 60.513 mow-e I‘mlo VCLCGVHL oriflné -) Q/e/ocgzfl‘zd. 3 Met/«[5 => Cone/Ucé’cg . on-Féllec‘ Mala/Ari of: E ' eQC/mns _ -/l/eZa//oic/S => Sém:‘—conc/uclérs 1. cone/acidifi/j rmwases 43 Want [fie/Yaw s A D Un—R'M 7 . [3 smau) emel'TbnS CCU/1 ems” be. J ink; VcLfif-Mk' de‘ocahzzc‘ orbi‘l‘agls. M 2') LSu/QIZOFS LU" ’ ) #OWWC/S 110/: {WM/1 F554,: A un- x/ac/ _ D p 7:) Veg G/‘Ffiku/K 243 excite? M (3Q;an > Am 4 A #4 UI’I-lcu‘flac/ Amt. ) ’“7‘ 37° % meal C2) an: /e‘ss MJ—MO/‘Q. due, 1‘9 fie. nee 60/ [4 firm A (:5) [a Coara’rfson 71b X23) {chifl)8r:I—)v E F . ‘ N! H Nam + '3. H103) ) u‘ “H a all: 17"? TUL-z 80%— OH“ ‘08 V &u‘|_A -13 a.” + HUD > “00 + R)“ my V 1:. - mm T Nays) bHFz‘ECIL NCLCS) + 15. Cl?- C%'\ > “6“ ($3 a T UL: an“ L2.\ — 1- Allr; [0‘8 42.14.95 ~3H¢l > Char. NM“ C‘Cm \J rE‘zLIQ'S.? '- Ck {on - ’ a. /’ gong A‘NMAA‘OA £631wa m/Oms ® COL/tn it EOFU :44 JIM 2-.) C‘C. £3000! IFS [EL/é kT/mol) ano/ SI‘MIr/M ,4) c—x (ex. C—oj-stI/mi) MO/ 'fius 0(— Acne/Z am rc/chr'V-e/J sAéCL, -flus clam Gmc/ f/‘nj SAP“ “5 fiat-m . @ ® {0: 66} ED .8 [.6wa ‘ N EN —— O ‘ (=--> J” 3"} Zoo“ structh ® Cll> (SFL vFl 73:; :? W@u\d exPecA' .F-L +0 ‘AGLv-Q 31%“ 5‘— ‘oon’ih 3'22. oF‘ OLl'LfiU—kbh win an OK RM.) chLLOI-S)ONL_ 0? wer« 215. "(M dk‘sWLJL o? \oomlx‘nj Parr 0P QLQC—I‘I'OAS \‘D 'HNL LvUO hucisL} (bani m1¥k3 :7 FL M063 skorCZer bond. rePzL Eou‘JA OHM—P _oL$ Bong LQASHN Ts Sc) 00 00 '2 —F‘«2 E“ m ’ _ '7 MFuleOn . :3 QLPLASMA weal/.216 \aand Subs\m\-{‘0~\\\3. :7 Lone. Pod rs Shot"? © in 100%“an ‘30)n‘—5 for vafb ‘8 ebb/“MB He. Ne. Ar Kr Xe. fin (K) (4.2. 27 87 I10 [68" 2M balling Pornl’ inCY‘QOLS-Q clown gn'vuf) 1:7 malt [fl Zara [OM PC. in z) Lane/on (#g/wfsfbn gags =7 BCMam c/own (7me as fob/'mérr/"fi VIC/“34925 ...
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CHEM 230 Problem Set #8_key - CHEM 230: Problem Set #8...

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