ACS Review 4 Alcohols and Alkyl Halides

ACS Review 4 Alcohols and Alkyl Halides - ACS Review...

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ACS Review Alcohols and Alkyl Halides 1. What is the IUPAC name of the compound below? A. 5,5-dimethyl-2-hexanol B. 2,2-dimethyl-5-hexanol C. 5,5-dimethyl-2-pentanol D. 2,2-dimethyl-5-pentanol 2. What is the IUPAC name of the compound below? A. 3-isobutyl-2-hexanol B. 2-methyl-5-(1-hydroxyethyl)octane C. 2-methyl-5-propyl-6-heptanol D. 6-methyl-3-propyl-2-heptanol 3. What is the IUPAC name of the compound below? A. 8-chloro-4-isopropyl-4,7-dimethylnonane B. 2-chloro-6-isopropyl-3,6-dimethylnonane C. 2-chloro-3,6,7-trimethyl-6-propyloctane D. 6- sec -butyl-2-chloro-3,6-dimethyloctane 4. Rank the following three compounds in order of increasing boiling point. I. CH 3 CH 2 CH 3 II. CH 3 CH 2 OH III. CH 3 OCH 3 A. I < II < III B. I < III < II C. II < III < I D. II < I < III 5. What is the IUPAC name of the following compound? A. cis -3-methylcyclohexanol B. trans -3-methylcyclohexanol
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C. cis -5-methylcyclohexanol D. trans -5-methylcyclohexanol 6. Which of the following is isobutyl alcohol? A. CH 3 CH 2 CH 2 CH 2 OH B. CH 3 CH 2 CH(OH)CH 3 C. (CH 3 ) 2 CHCH 2 OH D. (CH 3 ) 3 COH 7. Identify the tertiary alcohol(s). A. only I B. only II C. only III D. both I and III 8. Identify the tertiary halide(s). A. I and II B. II and III C. III and IV D. only IV 9. What is the hybridization of the oxygen atom in alcohols? A. sp B. sp C. sp 2 D. sp 3 10. What is the nucleophile in the following substitution reaction?
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A. A B. B C. C D. D 11. The C-O-H bond angle in alcohols is closest to: A. 90 o B. 109.5 o C. 120 o D. 180 o 12. Rank the following alcohols in order of increasing reaction rate with HBr.
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This note was uploaded on 12/17/2010 for the course CHEM 101 taught by Professor Silva during the Spring '08 term at Binghamton University.

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ACS Review 4 Alcohols and Alkyl Halides - ACS Review...

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