ACS Review 14 Organometallic Compounds

ACS Review 14 Organometallic Compounds - ACS Review...

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ACS Review Organometallic Compounds Student: _________________________________________________________ 1. Which one of the following would not be a suitable solvent for Grignard reagents? A. CH 3 CH 2 OCH 2 CH 3 , diethyl ether B. CH 3 CH 2 OH, ethanol C. tetrahyrofuran (THF) D. they would all be suitable solvents 2. What are the products of the following sequence of reactions? A. 2-butanol and Mg(OH)Br B. 2-butanol and MgHBr C. butane and Mg(OH)Br D. butane and MgHBr 3. Which of the following has the largest acid dissociation constant, K a ? A. CH 3 CH 3 B. H 2 C=CH 2 C. HC CH D. CH 3 CH 2 OH 4. Arrange the following in order of decreasing basicity (most basic first). I. CH 3 CH 2 MgBr II. HC CMgBr III. CH 3 CH 2 OMgBr A. I > II > III B. I > III > II C. III > II > I D. II > I > III 5. Select the strongest base in the following. A. NaNH 2 B. CH 3 Li C. NaOCH 2 CH 3 D. HC CNa 6. Which of the following reaction sequences would convert 2-butanol into the deuterated compound below?
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A. A B. B C. C D. D 7. What is the major product of the following reaction? A. 2-ethyl-1-pentanol B. 2-ethyl-1-butanol C. 3-pentanol D. 3-methyl-1-pentanol 8. The reaction of phenylmagnesium bromide (C 6 H 5 MgBr) with propanal (CH 3 CH 2 CH=O), followed by hydrolysis yields: A. 2-phenyl-1-propanol B.
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ACS Review 14 Organometallic Compounds - ACS Review...

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