ACS Review 15 Alcohols Diols and Thiols

ACS Review 15 Alcohols Diols and Thiols - ACS Review...

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ACS Review Alcohols Diols and Thiols 1. Which of the following cannot be made by the reduction of a ketone or aldehyde with NaBH 4 in methanol? A. 1-butanol B. 2-butanol C. 2-methyl-1-propanol D. 2-methyl-2-propanol 2. An alcohol has the same oxidation state as a(n): A. ketone B. alkene C. organolithium compound D. alkyl halide 3. In general, the reduction of a ketone to an alcohol can be accomplished by all of the following except one. Which one will not reduce a ketone? A. H 2 /Pt B. HIO 4 C. LiAlH 4 D. NaBH 4 4. What is the product of the following reaction? A. A B. B C. C D. D 5. Which one of the following is not readily oxidized by K 2 Cr 2 O 7 in H 2 SO 4 /H 2 O? A. n-butyl alcohol B. sec -butyl alcohol C. isobutyl alcohol D. tert -butyl alcohol 6. In general, which one of the functional groups below does not react with LiAlH 4 ? A. esters B. ketones C. ethers D. carboxylic acids 7. Give the product of the following reaction.
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A. A B. B C. C D. D 8. Which of the following reagents would be used to carry out the transformation shown below? A. NaBH 4 B. LiAlH 4 C. H 2 /Pt D. PCC/CH 2 Cl 2 9. The reaction of a Grignard reagent with ethylene oxide followed by dilute acid gives: A.
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This note was uploaded on 12/17/2010 for the course CHEM 101 taught by Professor Silva during the Spring '08 term at Binghamton University.

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ACS Review 15 Alcohols Diols and Thiols - ACS Review...

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