{[ promptMessage ]}

Bookmark it

{[ promptMessage ]}

PA2-1 - 1 The Gibbs expression for entropy is given by S...

Info iconThis preview shows page 1. Sign up to view the full content.

View Full Document Right Arrow Icon
Background image of page 1
This is the end of the preview. Sign up to access the rest of the document.

Unformatted text preview: 1. The Gibbs expression for entropy is given by S = -k (In Pa”) (1) and the canonical distribution is given by _E (N.V) P307, T, N) = m (2) (a) Show that the Helmholtz free energy F is given in terms of the canonical partition fimction Z as ' F = —len Z (3) L—I (b) Exprees the pressure p in terms of the canonical partition function Z (c) The natural logarithm of the canonical partition function of the ideal gas is givenby , ka We an=Nln[(21rh2) W] (4) Derive the ideal gas equation (R = N k). ...
View Full Document

{[ snackBarMessage ]}